新型炭材料(中英文)2025,Vol.40Issue(4):717-737,21.DOI:10.1016/S1872-5805(25)61025-0
钾离子电池传统碳负极材料的研究进展、挑战与展望
Conventional carbon anodes for potassium-ion batteries:Progress,challenges and prospects
摘要
Abstract
As an emerging electrochemical energy storage techno-logy,potassium-ion batteries(PIBs),which are considered a"bey-ond Li-ion"battery system,have attracted tremendous attention due to their potential for providing a high energy density,and having abundant resource,and a low cost.However,their commercializa-tion is hindered by the lack of practical anode materials.Among various reported anodes,conventional carbon materials,including graphite,soft carbon,and hard carbon,have emerged as promising candidates because of their abundance,low cost,high conductivity,and tunable structures.However,these materials have problems such as a low initial Coulombic efficiency,significant volume expansion,and unsatisfactory cyclability and rate performance.Various strategies to solve these have been explored,including optimizing the interlayer spacing,structural design,surface coating,constructing a multifunctional framework,and forming composites.This review provides a comprehensive overview of the recent progress in conventional carbon anodes,highlighting structural design strategies,mechanisms for improving the electrochemical performance,and underscores the critical role of these materi-als in promoting the practical application of PIBs.关键词
钾离子电池/碳负极/石墨/软炭/硬炭Key words
Potassium-ion batteries/Carbon anode/Graphite/Soft carbon/Hard carbon分类
化学化工引用本文复制引用
曹斌,崔峥,刘欢,张双印,徐斌..钾离子电池传统碳负极材料的研究进展、挑战与展望[J].新型炭材料(中英文),2025,40(4):717-737,21.基金项目
This work was supported by the National Key Research and Development Program of China(2022YFB2404402),National Natural Science Found-ation of China(52273274 and 52072021),the Natural Science Basis Research Plan in Shaanxi Province of China(2025JC-YBMS-12),the opening Foundation of State Key Laboratory of Organic-Inorganic Com-posites,Beijing University of Chemical Technology(oic-202501012)and Outstanding Youth Science Fund of Xi'an University of Science and Technology. 国家重点研发计划(2022YFB2404402) (2022YFB2404402)
国家自然科学基金(52273274,52072021) (52273274,52072021)
陕西省自然科学基础研究计划((2025JC-YBMS-12) ((2025JC-YBMS-12)
北京化工大学有机无机复合材料国家重点实验室开放课题(oic-202501012)及西安科技大学优秀青年基金资助项目. (oic-202501012)