新型炭材料（中英文）2025，Vol.40Issue(4)：889-908,20.DOI:10.1016/S1872-5805(25)61016-X
锂硫电池催化的活性与稳定性平衡策略
Strategies for balancing catalytic activity and stability in lithium-sulfur batteries
摘要
Abstract
Lithium-sulfur(Li-S)batteries have great promise for next-generation energy storage devices due to the high theoretical specific capacity(1675 mAh g-1)of sulfur with chemical conver-sion for charge storage.However,their practical use is hindered by the slow redox kinetics of sulfur and the"shuttle effect"arising from dissolved lithium polysulfides(LiPSs).In recent years,vari-ous carbon-based materials have served as sulfur hosts and cata-lysts for accelerating sulfur conversion redox kinetics and alleviat-ing LiPS shuttling.However,they often suffer from irreversible passivation and structural changes that destroy their long-term performance.We consider the main problems limiting their stabil-ity,including excessive LiPS adsorption,passivation by insulat-ing Li2S,and surface reconstruction,and clarify how these factors lead to capacity fade.We then outline effective strategies for achieving long-term sulfur catalysis,focusing on functional car-bon,such as designing suitable carbon-supported catalyst inter-faces,creating well-distributed active sites,adding cocatalysts to improve electron transfer,and using carbon-based protective layers to suppress unwanted side reactions.Using this information should enable the development of stable,high-activity catalysts capable of long-term operation under practical conditions in Li-S batteries.关键词
锂硫电池/催化/催化剂中毒/催化活性/催化稳定性Key words
Lithium-sulfur batteries/Catalysis/Catalyst poisoning/Catalytic activity/Catalytic stability分类
化学化工引用本文复制引用
彭琳凯,史济炜,曹赟,兰佳琦,耿传楠,吕伟..锂硫电池催化的活性与稳定性平衡策略[J].新型炭材料（中英文）,2025,40(4):889-908,20.基金项目
This work was supported by the National Key R&D Program of China(2021YFF0500600),the Na-tional Natural Science Foundation of China(U23B2077),Guangdong Basic and Applied Basic Research Foundation(2023B1515120047),Shenzhen Science and Technology Program(JCYJ2022081810-1008018 and KJZD20240903100900002). 国家重点研发计划(2021YFF0500600) （2021YFF0500600）
国家自然科学基金(U23B2077) （U23B2077）
广东省基础与应用基础研究基金(2023B1515120047) （2023B1515120047）
深圳市科技计划(JCYJ20220818101008018、KJZD20240903100900002). （JCYJ20220818101008018、KJZD20240903100900002）
