含能材料2025，Vol.33Issue(8)：847-859,13.DOI:10.11943/CJEM2025053
基于有机硅包覆HMX的推进剂界面增强研究
Interfacial Enhancement Technology of Propellant Based on Silicone-coated HMX
摘要
Abstract
To enhance the mechanical properties of HTPB four-composite solid propellants,3-[2-(2-aminoethylamino)ethylami-no]propyl-trimethoxysilane(A1130)and N-(Triethoxysilylpropyl)urea(A1160)were employed to modify the surface of HMX and qy-HMX,followed by their application in solid propellant formulation.Scanning electron microscope(SEM),X-ray diffrac-tion(XRD),X-ray photoelectron spectroscopy(XPS),atomic force microscope(AFM)and thermal analysis(DSC-TG)were used to test the morphology,structure and performance of samples.The interfacial enhancement effects were systematically in-vestigated using an electronic universal testing machine and dynamic thermomechanical analyzer(DMA)to assess mechanical properties and adhesion characteristics.Results demonstrate that the silane treatment forms continuous coating layers without changing the crystalline structure.Silane coating inhibits effectively the transformation of HMX,increasing the phase transition temperature of HMX@A1130 and HMX@A1160 to 193.9℃and 201.4℃,which are 2.3℃and 9.8℃higher than that of raw HMX.The mechanical tests reveal significant improvements in propellant tensile strength across both high temperature(70℃)and low temperature(-50℃)conditions.Notably,A1130-modified propellant exhibits an enhanced tensile strength with the adhesion index reduced from 1.52 to 1.24 at-50℃/500 mm·min-1.The tensile strength of propellants modified with HMX@A1130 and HMX@A1160 increases by 29.9%and 31.6%,and the maximum elongation increase by 29.9%and 31.6%,respectively.DMA results show that the peak value of loss factor for the A1130-modified propellant decreases from 0.51 to 0.47,indicating a mitigation of the interfacial'dewetting'phenomenon at low temperatures.The fracture surface morphology analysis results are in good agreement with the tensile test and DMA test.The addition of two silane coupling agents has a significant inter-facial modification effect,and A11330 can inhibit the interfacial'dewetting'on hydroxyl-terminated polybutadiene system.关键词
表面包覆/硅烷偶联剂/奥克托今(HMX)/丁羟四组元推进剂/力学性能Key words
surface coating/silane coupling agent/octogen(HMX)/HTPB propellants/mechanical properties分类
军事科技引用本文复制引用
覃元,蒲睿,涂珑潇,严启龙..基于有机硅包覆HMX的推进剂界面增强研究[J].含能材料,2025,33(8):847-859,13.基金项目
国家自然科学基金(U2030202) National Nature Science Foundation of China(No.U2030202) （U2030202）
