低碳化学与化工2025，Vol.50Issue(8)：106-122,17.DOI:10.12434/j.issn.2097-2547.20250108
丙烷脱氢制丙烯用金属氧化物/分子筛催化剂研究进展
Research progress of metal oxide/zeolite catalysts for propane dehydrogenation to propylene
摘要
Abstract
The reaction of propane dehydrogenation to propylene has the advantages of abundant raw material sources,simple product compositions and easy separation.It is one of the most promising methods for propylene production.Traditional Pt-based catalysts have problems such as high cost and easy sintering.In recent years,molecular sieves have been considered as one of the ideal carriers for loading active species of metal oxides due to their ordered pore structures,high specific surface areas,good thermal stabilities and adjustable acidities.The structural regulation strategies of the active sites of metal(such as Cr,Ga and Zn)oxide catalysts were summarized,and the applications of common molecular sieves in propane dehydrogenation to propylene were introduced in detail starting from different topological structures.Finally,the future development directions of metal oxide/molecular sieve catalysts were prospected.关键词
丙烷脱氢制丙烯/金属氧化物/分子筛/结构调控/多相反应Key words
propane dehydrogenation to propylene/metal oxide/molecular sieves/structure regulation/heterogeneous reaction分类
化学化工引用本文复制引用
代怡,王凯杰,张耀远,吴芹,史大昕,陈康成,杨彦鹏,黎汉生..丙烷脱氢制丙烯用金属氧化物/分子筛催化剂研究进展[J].低碳化学与化工,2025,50(8):106-122,17.基金项目
国家能源石油炼制技术研发中心(中石化石油化工科学研究院有限公司)开放基金 （中石化石油化工科学研究院有限公司）
中国石油天然气股份有限公司科技开发项目(2023ZZ36) （2023ZZ36）
重质油全国重点实验室开放基金 （）
北京理工大学青年教师学术启动计划. （）
