无机材料学报2025,Vol.40Issue(7):735-746,12.DOI:10.15541/jim20240333
钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展
Research Progress on Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides
摘要
Abstract
Control and removal of volatile organic compounds(VOCs)have always been critical issues in the environmental field.Catalytic oxidation has emerged as one of the most promising technologies for VOCs removal due to its low operational temperature,high efficiency,and non-toxic by-products.Perovskite oxides(ABO3)are recognized as efficient and stable catalysts for the catalytic oxidation of VOCs.To enhance the catalytic efficiency of perovskite-based catalysts,it is necessary to systematically analyze and optimize the design of perovskite oxides to meet the specific requirements for the removal of different VOCs.This paper comprehensively reviews recent advances in the catalytic oxidation of VOCs using perovskite oxides.Firstly,various design strategies for perovskite oxides in the catalytic oxidation of VOCs,including morphology control,A-site and B-site substitution,defect engineering,and supported perovskite catalysts,are introduced,giving a close link between the catalytic performance of perovskite oxides and their material composition,morphology,surface properties(oxygen species,defects),and intrinsic properties(oxygen vacancy concentration,lattice structure).The reaction mechanisms and degradation pathways involved in the catalytic oxidation of VOCs are analyzed,and the prospects and challenges in the rational design of perovskite oxide catalysts and the exploration of reaction mechanisms are outlined.关键词
挥发性有机化合物/钙钛矿型氧化物/结构设计/催化氧化/综述Key words
volatile organic compound/perovskite oxide/structure design/catalytic oxidation/review分类
化学化工引用本文复制引用
朱文杰,唐璐,陆继长,刘江平,罗永明..钙钛矿型氧化物催化氧化挥发性有机化合物的研究进展[J].无机材料学报,2025,40(7):735-746,12.基金项目
国家自然科学基金(22166021) (22166021)
云南省科技厅科技计划(202302AG050002-1) (202302AG050002-1)
云南省中青年学术与技术带头人后备人才(202405AC350026)National Natural Science Foundation of China(22166021) (202405AC350026)
Science and Technology Plan Project of Yunnan Provincial Science and Technology Department(202302AG050002-1) (202302AG050002-1)
Yunnan Province Reserve Talent Project for Young and Middle-aged Academic and Technical Leaders(202405AC350026) (202405AC350026)