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纳米化和Cr含量对Co-Fe-Cr合金在NaCl溶液中腐蚀行为的影响

张昊鑫 王秀 韩漾 曹中秋 张轲 王艳

有色金属科学与工程2025,Vol.16Issue(4):503-509,7.
有色金属科学与工程2025,Vol.16Issue(4):503-509,7.DOI:10.13264/j.cnki.ysjskx.2025.04.001

纳米化和Cr含量对Co-Fe-Cr合金在NaCl溶液中腐蚀行为的影响

Influences of nano crystallization and Cr content on corrosion behavior of Co-Fe-Cr alloy in NaCl solutions

张昊鑫 1王秀 1韩漾 1曹中秋 1张轲 1王艳1

作者信息

  • 1. 沈阳师范大学化学化工学院,沈阳 110034
  • 折叠

摘要

Abstract

The conventional and nanometer-sized powders prepared by powder metallurgy(PM)and mechanical alloying(MA)were pressed into PM,MA Co-20Fe-20Cr and PM,MA Co-20Fe-30Cr bulk alloys using vacuum hot-pressing technology.The corrosion behavior of these alloys in 0.5 mol/L NaCl solution and the influence of nano crystallization and Cr content were investigated by electrochemical testing technology.The results show that under the experimental conditions,the corrosion current densities of the two nanometer alloys decreased by 5.066 9 μA/cm2 and 1.670 3 μA/cm2,and the charge transfer resistances increased by 29 675 Ω/cm2 and 30 947 Ω/cm2,respectively,compared with their conventional-sized counterparts.Nano crystallization can improve the corrosion properties of the alloys.Moreover,the corrosion current densities of the two Co-20Fe-30Cr alloys decreased by 3.5811 μA/cm2 and 0.184 5 μA/cm2,and the charge transfer resistances increased by 10 633 Ω/cm2 and 11 905 Ω/cm2,respectively,compared with those of the corresponding Co-20Fe-20Cr alloys.A 10%increase in Cr content improves corrosion performance.

关键词

Co-Fe-Cr合金/纳米化/Cr含量/腐蚀行为

Key words

Co-Fe-Cr alloy/nanocrystalline/Cr content/corrosion behavior

分类

矿业与冶金

引用本文复制引用

张昊鑫,王秀,韩漾,曹中秋,张轲,王艳..纳米化和Cr含量对Co-Fe-Cr合金在NaCl溶液中腐蚀行为的影响[J].有色金属科学与工程,2025,16(4):503-509,7.

基金项目

国家自然科学基金资助项目(51271127) (51271127)

辽宁省重点研发计划资助项目(2018304025) (2018304025)

有色金属科学与工程

OA北大核心

1674-9669

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