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基于超分子氢键动态网络的高强度自修复弹性体材料的制备与性能研究

芮国芬 王东

塑料科技2025,Vol.53Issue(8):35-38,4.
塑料科技2025,Vol.53Issue(8):35-38,4.DOI:10.15925/j.cnki.issn1005-3360.2025.08.007

基于超分子氢键动态网络的高强度自修复弹性体材料的制备与性能研究

Preparation and Properties Study of High-strength Self-healing Elastomers Material Based on Supramolecular Hydrogen-bonded Dynamic Networks

芮国芬 1王东2

作者信息

  • 1. 常州大学怀德学院,江苏 泰州 214500
  • 2. 常州大学材料科学与工程学院,江苏 常州 213164
  • 折叠

摘要

Abstract

A novel self-healing polyurethane-urea elastomer was designed by leveraging the reversible,dynamic network of supramolecular hydrogen bonds,with 4,4′-diaminobenzanilide(DABA)serving as the chain extender.The amino groups of DABA react with isocyanate to form rigid segments,while its aromatic backbone and strong urea-type hydrogen bonds enhance mechanical performance.The resulting elastomer exhibits an outstanding tensile strength of 7.15 MPa and excellent elasticity,achieving a healing efficiency of 99.5%after 30 min at 90℃.The study offers a facile strategy for fabricating high-performance,self-healing polyurethane-urea elastomers.

关键词

氢键/弹性体/自修复

Key words

Hydrogen bonds/Elastomer/Self-healing

分类

化学化工

引用本文复制引用

芮国芬,王东..基于超分子氢键动态网络的高强度自修复弹性体材料的制备与性能研究[J].塑料科技,2025,53(8):35-38,4.

基金项目

江苏省自然科学基金青年基金项目(BK20240981) (BK20240981)

常州市应用基础研究计划项目(CJ20240040) (CJ20240040)

塑料科技

OA北大核心

1005-3360

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