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位阻胺脱硫溶剂抗发泡性能及工业应用验证

朱玥嘉 周志斌 朱道平 汪东 郭本帅

天然气与石油2025,Vol.43Issue(4):20-25,6.
天然气与石油2025,Vol.43Issue(4):20-25,6.DOI:10.3969/j.issn.1006-5539.2025.04.003

位阻胺脱硫溶剂抗发泡性能及工业应用验证

Antifoaming performance and industrial application validation of sterically hindered amine desulfurization solvent

朱玥嘉 1周志斌 1朱道平 1汪东 1郭本帅1

作者信息

  • 1. 中国石化南京化工研究院,江苏 南京 210048
  • 折叠

摘要

Abstract

This study investigates the foaming properties of sterically hindered amine desulfurization solvent in natural gas purification processes when exposed to oil,salts,and solid particulate impurities,aiming to assess their antifoaming performance and conducted industrial application experiment of sterically hindered amine desulfurization solvent in natural gas purification plants.By simulating polluted conditions,a foaming experiment device with a nitrogen flow rate of 400 mL/min and a water bath temperature of 40℃was used.Various proportions of produced water from gas fields,as well as particulate impurities of different concentrations and sizes(such as ferrous sulfide and activated carbon),were added to the sterically hindered amine desulfurization solvent.The foam height and defoaming time were measured and recorded.When exposed to oil-containing produced water and large particulate impurities,the sterically hindered amine solution showed excellent antifoaming performance,with foam heights consistently below 5 cm and defoaming times significantly less than 5 seconds,outperforming traditional reference solvents.The sterically hindered amine desulfurization solvents significantly enhance the antifoaming properties of amine solutions through multiple mechanisms.Industrial application trials further verified the long-term antifoaming performance of the sterically hindered amine desulfurization solvent.The superior antifoaming capability of the sterically hindered amine desulfurization solvent effectively mitigates foaming issues during natural gas purification,thereby improving production efficiency and providing strong support for its industrial application.

关键词

天然气/净化/位阻胺/泡沫高度/消泡时间

Key words

Natural gas/Purification/Sterically hindered amine/Foaming height/Defoaming time

引用本文复制引用

朱玥嘉,周志斌,朱道平,汪东,郭本帅..位阻胺脱硫溶剂抗发泡性能及工业应用验证[J].天然气与石油,2025,43(4):20-25,6.

基金项目

国家重点研发计划"区域CO2捕集与封存关键技术研发与示范"(2022YFE0206800) (2022YFE0206800)

天然气与石油

1006-5539

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