西北师范大学学报（自然科学版）2025，Vol.61Issue(5)：4-21,18.DOI:10.16783/j.cnki.nwnuz.2025.05.002
无机磷(酸盐)活化转化为有机膦化合物的最新研究进展
Recent advances in the activation and conversion of inorganic phosphorus(phosphates) to organophosphorus compounds
摘要
Abstract
This paper systematically reviews the cutting-edge research advances in the activation and conversion of inorganic phosphorus(phosphates)to organophosphorus compounds in recent years.Firstly,it summarizes the innovative strategies for the direct activation of white phosphorus(P4)to synthesize organophosphorus compounds.Secondly,it explores the latest research achievements in the application of Na(OCP)in the preparation of organophosphorus(heterocyclic)compounds.Finally,it introduces the recent progress in the reductive conversion of phosphates and activation conversion with preserved oxidation state,with a focus on the synthesis of[TBA][P(SiCl3)2]and[TBA][PO2X2]as well as their synthetic applications.The paper prospects the future application potential of phosphates as a natural phosphorus source,highlighting that their direct utilization is expected to break the dependence of traditional processes on white phosphorus,and achieve a green conversion process from phosphate rock to phosphates and then to functional organophosphorus compounds.关键词
Na(OCP)/[TBA][PO2X2]/[TBA][P(SiCl3)2]Key words
Na(OCP)/[TBA][PO2X2]/[TBA][P(SiCl3)2]分类
化学化工引用本文复制引用
柴垚,田雅玲,权正军..无机磷(酸盐)活化转化为有机膦化合物的最新研究进展[J].西北师范大学学报（自然科学版）,2025,61(5):4-21,18.基金项目
国家自然科学基金资助项目(22571258,22061038) （22571258,22061038）
甘肃省高校产业支持计划项目(No.2024CYZC-08) （No.2024CYZC-08）
甘肃省自然科学基金资助项目(25ZDWA008) （25ZDWA008）
