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Dynamic nuclear polarization and chemically induced hyperpolarization:Progress,mechanisms,and opportunities

Danhua Dai Yangping Liu Xiao He Jiafei Mao

磁共振快报（英文）2025，Vol.5Issue(3)：23-49,27.

磁共振快报（英文）2025，Vol.5Issue(3)：23-49,27.DOI:10.1016/j.mrl.2025.200178

Dynamic nuclear polarization and chemically induced hyperpolarization:Progress,mechanisms,and opportunities

Danhua Dai ¹Yangping Liu ²Xiao He ³Jiafei Mao⁴

作者信息

1. Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development,Shanghai Frontiers Science Center of Molecule Intelligent Syntheses,School of Chemistry and Molecular Engineering,East China Normal University,Shanghai,200062,China
2. Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics,School of Pharmacy,Tianjin Medical University,Tianjin,300070,China
3. Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development,Shanghai Frontiers Science Center of Molecule Intelligent Syntheses,School of Chemistry and Molecular Engineering,East China Normal University,Shanghai,200062,China||Chongqing Key Laboratory of Precision Optics,Chongqing Institute of East China Normal University,Chongqing,401120,China||New York University-East China Normal University Center for Computational Chemistry,New York University Shanghai,Shanghai,200062,China
4. Huairou Research Center and Beijing National Laboratory for Molecular Sciences(BNLMS),Institute of Chemistry,Chinese Academy of Sciences,Yongle Street 1,Yanqi Town,Beijing,101407,China
折叠

摘要

关键词

Dynamic nuclear polarization(DNP)/NMR spectroscopy/Chemically induced dynamic nuclear polar-ization(CIDNP)/Radical/Cross effect/Solid effect/Overhauser effect

Key words

Dynamic nuclear polarization(DNP)/NMR spectroscopy/Chemically induced dynamic nuclear polar-ization(CIDNP)/Radical/Cross effect/Solid effect/Overhauser effect

引用本文复制引用

Danhua Dai,Yangping Liu,Xiao He,Jiafei Mao..Dynamic nuclear polarization and chemically induced hyperpolarization:Progress,mechanisms,and opportunities[J].磁共振快报（英文）,2025,5(3):23-49,27.

基金项目

D.D.was supported by the National Natural Science Foundation of China(Grant No.22403029)and the Postdoctoral Fellowship Program of China Postdoctoral Science Foundation(Grant No.GZC20240475,2024M760922).Y.L.was supported by National Natural Science Foundation of China(Grant No.22174099).X.H.was supported by the National Natural Science Foundation of China(Grant No.22273023),the National Key R&D Program of China(Grant No.2019YFA0905200),Shanghai Municipal Natural Science Foundation(Grant No.23ZR1418200),Natural Science Foundation of Chongqing,China(Grant No.CSTB2023NSCQ-MSX0616),Shanghai Frontiers Science Center of Molecule Intelligent Syntheses,and the Fundamental Research Funds for the Central Universities.J.M.thanks the Institute of Chemistry,Chinese Academy of Sciences(ICCAS)and Beijing National Laboratory for Molecular Sciences(BNLMS)for the career support.We also thank Dr.Andrei Kuzhelev for advice on the manuscript. （Grant No.22403029）

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