含能材料2025，Vol.33Issue(9)：993-1004,12.DOI:10.11943/CJEM2025100
全氮离子及长氮链含能材料研究进展
Research Progress of All-nitrogen Ions and Long Nitrogen Chains Energetic Materials
摘要
Abstract
Nitrogen-rich energetic compounds have received a lot of attention in the research fields of propellants,explosives and gas generant thanks to their high enthalpy of formation and clean decomposition products.However,as a significant branch of nitrogen-rich energetic materials,research and development on the compounds with all-nitrogen and chain-like nitrogen struc-tures are hampered by the lack of suitable nitrogen sources and efficient synthetic methods for the construction of nitrogen chain backbone.In this review,the design ideas,synthetic methods,and breakthrough progress of all-nitrogen ionic energetic com-pounds and long nitrogen chains energetic materials containing at least six nitrogen atoms linked together are systematically ana-lyzed,and the references for the design and development of milestone high energy density materials are offered.关键词
五唑阴离子/链状氮原子/合成/爆轰性能Key words
pentazole anion/catenated nitrogen atom chains/synthesis/detonation performances分类
军事科技引用本文复制引用
许泽,陆明..全氮离子及长氮链含能材料研究进展[J].含能材料,2025,33(9):993-1004,12.基金项目
国家自然科学基金(22135003,22475102) National Natural Science Foundation of China(Nos.22135003,22475102) （22135003,22475102）
