常州大学学报（自然科学版）2025，Vol.37Issue(5)：1-7,7.DOI:10.3969/j.issn.2095-0411.2025.05.001
硼掺杂磷化钴催化剂的构筑及电催化析氧性能
Preparation and electrocatalytic oxygen evolution performance of B-doped CoP catalyst
摘要
Abstract
Water electrolysis is an efficient,clean,and sustainable method for hydrogen production,the development of cost-effective oxygen evolution reaction(OER)catalysts has become the key to a-chieving large-scale hydrogen production in water electrolysis industry.To prepare efficient OER elec-trocatalysts,a new type of non-metallic boron(B)doped cobalt phosphide(CoP)electrocatalyst was prepared by combining wet chemical method with low-temperature phosphating method.The prepared B-CoP catalyst possesses a large specific surface area.Moreover,B doping can effectively regulate the electronic structure of CoP,optimize the binding energy of oxygen-containing intermediates,reduce the reaction energy barrier of OER rate determination steps,and enable it to exhibit excellent electro-catalytic oxygen evolution performance.关键词
析氧反应/掺杂/电子结构/磷化钴Key words
oxygen evolution reaction/doping/electronic structure/cobalt phosphide分类
化学化工引用本文复制引用
徐辉,金磊,陈海群..硼掺杂磷化钴催化剂的构筑及电催化析氧性能[J].常州大学学报（自然科学版）,2025,37(5):1-7,7.基金项目
国家自然科学基金资助项目(22305025) （22305025）
常州大学人才引进资助项目(ZMF22020055). （ZMF22020055）
