燃料化学学报（中英文）2025，Vol.53Issue(9)：1300-1319,20.DOI:10.1016/S1872-5813(25)60595-0
Mott-Schottky基电解水催化剂研究进展
Mott-Schottky electrocatalysts for water splitting
摘要
Abstract
The electron configuration of the active sites can be effectively modulated by regulating the inherent nanostructure of the electrocatalysts,thereby enhancing their electrocatalytic performance.To tackle the unexplored challenge of substantial electrochemical overpotential,surface reconstruction has emerged as a necessary strategy.Focusing on key aspects such as Janus structures,overflow effects,the d-band center displacement hypothesis,and interface coupling related to electrochemical reactions is essential for water electrolysis.Emerging as frontrunners among next-generation electrocatalysts,Mott-Schottky(M-S)catalysts feature a heterojunction formed between a metal and a semiconductor,offering customizable and predictable interfacial synergy.This review offers an in-depth examination of the processes driving the hydrogen and oxygen evolution reactions(HER and OER),highlighting the benefits of employing nanoscale transition metal nitrides,carbides,oxides,and phosphides in M-S heterointerface catalysts.Furthermore,the challenges,limitations,and future prospects of employing M-S heterostructured catalysts for water splitting are thoroughly discussed.关键词
莫特-肖特基电催化剂/水裂解/异质结构/半导体Key words
Mott-Schottky electrocatalysts/water splitting/heterojunctions/semiconductors分类
化学化工引用本文复制引用
潘婧,付丹飞,杨浩,罗必富,杨忠杰..Mott-Schottky基电解水催化剂研究进展[J].燃料化学学报（中英文）,2025,53(9):1300-1319,20.基金项目
The project was supported by the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2021L574),the Guizhou Provincial Science and Technology Foundation([2024]ZK General 425 and 438),the National Natural Science Foundation of China(22309033),and the Academic Young Talent Foundation of Guizhou Normal University([2022]B05 and B06). （2021L574）
