燃料化学学报（中英文）2025，Vol.53Issue(9)：1364-1372,中插15-中插26,21.DOI:10.1016/S1872-5813(25)60556-1
基于棒状锰基二维MOF材料的合成及其高效电催化氮氧化性能
High-performance electrocatalytic nitrogen oxidation of two-dimensional MOF based on a rod-manganese motifs
摘要
Abstract
The electrocatalytic nitrogen oxidation reaction(NOR)is a sustainable approach for converting N2 to NO3-under mild conditions.However,it still faces challenges including inefficient N2 absorption/activation and oxygen evolution competition,sluggish kinetics,low Faradaic efficiency,and limited nitrate yields.In this work,a novel two-dimensional(2D)layered MOF Mn-BCPPy(H2BCPPy=3,5-di(4'-carboxyphenyl)pyridine)has been successfully synthesized.The framework is composed of a rod-manganese motifs and possesses abundant active sites including open metal sites(OMSs)and Lewis base sites(LBSs).The Mn-BCPPy is the first MOF catalyst applied in electrocatalytic NOR which exhibited relatively high activity with a NO3-yield of 99.75 μg/(h·mg)and a Faraday efficiency(FE)of 32.09％.Furthermore,it can be used as fluorescent sensor for selectively and sensitively detect nitrofuran antibiotics(NFs).Therefore,this work explores the application of MOF materials in the field of electrocatalytic NOR,which reveals that manganese-based MOFs have great potential prospects.关键词
金属有机框架材料/电催化/氮气氧化/硝酸盐/荧光传感Key words
metal-organic framework/electrocatalytic/nitrogen oxidation/nitrate/fluorescence sensor分类
化学化工引用本文复制引用
姚晓艳,李权,赵翔宇,武铭瑞,刘立成,王文泰,姚硕..基于棒状锰基二维MOF材料的合成及其高效电催化氮氧化性能[J].燃料化学学报（中英文）,2025,53(9):1364-1372,中插15-中插26,21.基金项目
The project was supported by Natural Science Foundation of Shandong Province(ZR2021MB075)and Fundamental Research Funds for the Central Universities,Ocean University of China(202461021). （ZR2021MB075）
