溶磷菌Rs-5介导生物炭缓释磷肥磷素溶解与缓释效能调控机理OA
Mechanisms of phosphorus solubilization and slow-release efficacy of biochar slow-release phosphorus fertilizers mediated by phosphorus solubilizing bacterium Rs-5
为了提高土壤磷素的利用效率,通过调控H3PO4 加量与石榴枝条、Ca3(PO4)2,利用共热解方法制备生物炭缓释磷肥负载溶磷菌Rs-5精准调控磷的释放.采用细菌培养法结合扫描电子显微镜观察Rs-5在生物炭缓释磷肥表面的生长情况,并通过比表面积及孔隙分析仪测定生物炭缓释磷肥的比表面积和孔结构,探究其对Rs-5的吸附能力.利用傅里叶红外光谱和X射线衍射仪对生物炭基菌剂的表面官能团和晶形结构进行表征,为磷的溶解与释放提供依据.通过溶磷能力和释放实验证明Rs-5可以促进生物炭缓释磷肥中的难溶磷酸盐溶解释放,制备的生物炭基菌剂可以作为缓释磷肥稳定的为土壤提供磷源.结果表明:Rs-5的溶磷量达到389.24 mg/L,具有优良的溶磷效能,在生物炭缓释磷肥条件下能正常生长且均匀分布.H3PO4 加量越高,生物炭缓释磷肥的比表面积也越大,提供的吸附位点更多,更适合吸附Rs-5,与Rs-5的生物相容性越优异.生物炭基菌剂表面官能团丰富,生成Ca-P金属复合晶体,其结构缓释性能良好.H3PO4 加量越大,生物炭缓释磷肥与Rs-5联合培养后溶磷量越高,溶解难溶磷酸盐的能力越强,制备的生物炭基菌剂磷释放量越高,达到15.94 mg/g.释放模型符合拟二级动力学和Elovich模型.
In order to improve soil phosphorus use efficiency,it is crucial to develop sustainable strategies for slow release of phosphorus fertilizers.The biochar slow-release phosphate fertilizers loaded phosphorus solubilizing bacteria Rs-5 prepared by regulating H3PO4 addition with pome-granate branches and Ca3(PO4)2 using the co-pyrolysis method can accurately regulate the release of phosphorus,and Rs-5 can promote the release of insoluble phosphate solubilized in the BSR-PFs,and the biochar-based bacterial preparation can be used as a slow-release phosphorus fertiliz-er to steadily provide phosphorus source for the soil.The results showed that the dissolved phos-phorus amount of Rs-5 reached 389.24 mg/L,with excellent phosphorus solubilization efficiency,and it could grow normally and be evenly distributed under the condition of BSRPFs.The higher the dosage of H3PO4,the higher the specific surface area of BSRPFs,which provided more ad-sorption sites and was more suitable for the adsorption of Rs-5,and the more biocompatibility was excellent with Rs-5.The surface functional groups of the biochar-based bacterial fertilizer were a-bundant,generating Ca-P metal composite crystals,such as Ca8H2(PO4)3(OH),etc.,indicating that its structure has good slow-release properties.The larger the amount of H3PO4 added,the higher the amount of dissolved phosphorus in the co-cultivation of BSRPFs with Rs-5,the better the ability to dissolve insoluble phosphate,and the higher the amount of phosphorus release from the prepared biochar-based bacterial fertilizer was,up to 15.94 mg/g.The release model was con-sistent with the proposed secondary kinetics and Elovich model.
武占省;韩佳怡;王建稳;陈梦真
西安工程大学 环境与化学工程学院,陕西 西安 710048西安工程大学 环境与化学工程学院,陕西 西安 710048西安工程大学 环境与化学工程学院,陕西 西安 710048西安工程大学 环境与化学工程学院,陕西 西安 710048
资源环境
磷释放生物炭缓释磷肥Rs-5H3PO4调控溶解难溶磷
phosphorus releasebiochar slow-release phosphate fertilizer(BSRPFs)Rs-5H3PO4 regulationdissolve insoluble phosphorus
《西安工程大学学报》 2025 (5)
48-58,11
国家自然科学基金(22278325)陕西省秦创原"科学家+工程师"队伍(2022KXJ-137)陕西省高校青年创新团队(2022TD071)
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