复合材料科学与工程Issue(9)：1-7,7.DOI:10.19936/j.cnki.2096-8000.20250928.001
基于Pickering乳液法的石墨烯/PCM复合材料的制备与性能
Preparation and properties of graphene/PCM composites based on Pickering emulsion method
摘要
Abstract
As a typical phase change material(PCM)for energy storage,paraffin(PA)was found to possess shortcomings such as easy leakage and poor thermal conductivity,which had limited its large-scale market applica-tion.To address this issue,solidified paraffin/graphene(PaGr)composites were prepared by a one-step hydrother-mal method,in which PA served as the matrix phase change material and reduced graphene oxide(RGO)acted as the confining carrier.During the hydrothermal process,the Pickering emulsion,configured with GO as a stabilizer,facilitated the effective recombination of paraffin and graphene.XPS and Raman spectroscopy were employed to con-firm the successful conversion of GO into RGO during the hydrothermal reduction process.The microstructure,ther-mophysical properties,and structural stability of the PaGr composite PCM were characterized through optical mi-croscopy,DSC,and thermal cycling.The experimental results show that PaGr composites can effectively improve the shape instability and high thermal resistance caused by PA liquid leakage.Compared with pure PA,its thermal conductivity and structural stability are improved,which indicates that PaGr composites have broad application pros-pects in the field of PCM.关键词
相变材料/石蜡/氧化石墨烯/储能技术/Pickering乳液/导热性能/复合材料Key words
phase change materials/paraffin/graphene oxide/energy storage technology/Pickering emulsion/thermal conductivity/composites分类
通用工业技术引用本文复制引用
卓晴,王诗仪,赵伟,李明普,王煜祺,李媛媛,李英儒..基于Pickering乳液法的石墨烯/PCM复合材料的制备与性能[J].复合材料科学与工程,2025,(9):1-7,7.基金项目
湖北省教育厅科研项目(Q20211905) （Q20211905）
湖北民族大学超轻弹性体绿色制造国家民委重点实验室开放基金(KYPT0923001,KYPT0923005) （KYPT0923001,KYPT0923005）
