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热镀锌板表面白斑产生原因

李雪峰 王世宁 陈洁明 刘晓勇 郭海霞 徐宁

理化检验-物理分册2025,Vol.61Issue(10):5-8,12,5.
理化检验-物理分册2025,Vol.61Issue(10):5-8,12,5.DOI:10.11973/lhjy-wl250140

热镀锌板表面白斑产生原因

Reasons for white spots on the surface of hot-dip galvanized sheet

李雪峰 1王世宁 1陈洁明 2刘晓勇 2郭海霞 1徐宁1

作者信息

  • 1. 洛阳船舶材料研究所,洛阳 471023
  • 2. 洛阳船舶材料研究所,洛阳 471023||海洋腐蚀与防护全国重点实验室,洛阳 471023
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摘要

Abstract

After six months of storage,white spots were found on some areas of the surface of a hot-dip galvanized sheet.The causes of surface white spots on hot-dip galvanized sheets were analyzed using macroscopic observation,chemical composition analysis,scanning electron microscopy and energy spectrum analysis,X-ray diffraction analysis,metallographic examination.The results show that galvanized sheets were stored in a high-temperature,high humidity,and high salt marine atmospheric environment.The humid air condensed into a liquid film on some areas of the sheet surface,and Cl-adsorbed on the metal surface,resulting in an increase in the conductivity of the medium and a decrease in the resistance of the surface rust layer,and led to corrosion of the galvanized layer,generated ZnO corrosion products,and ultimately formed white spots on the sheet surface.The SO2 in the atmosphere also promoted the occurrence of corrosion.

关键词

热镀锌板/白斑/海洋大气腐蚀/氯离子/SO2

Key words

hot-dip galvanized sheet/white spot/marine atmospheric corrosion/chloridion/SO2

分类

通用工业技术

引用本文复制引用

李雪峰,王世宁,陈洁明,刘晓勇,郭海霞,徐宁..热镀锌板表面白斑产生原因[J].理化检验-物理分册,2025,61(10):5-8,12,5.

理化检验-物理分册

1001-4012

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