综合智慧能源2025,Vol.47Issue(10):10-25,16.DOI:10.3969/j.issn.2097-0706.2025.10.002
氨基固体氧化物燃料电池的研究进展与机遇
Research progress and opportunities in ammonia-fueled solid oxide fuel cells
摘要
Abstract
As a hydrogen energy carrier and zero-carbon fuel,ammonia is considered to have significant potential in clean energy power generation.The application status and future development directions of direct-ammonia solid oxide fuel cells(DA-SOFCs)are thoroughly discussed.DA-SOFCs are classified into oxygen-conducting(O-SOFCs)and proton-conducting(H-SOFCs)types.Their working principles are outlined,along with the selection of electrolyte and electrode materials and the ammonia decomposition process at the anode.The influence of electrolyte type,electrode materials,and operating temperature on cell performance is summarized.Performance differences and their underlying reasons among different DA-SOFC types using NH3 as fuel are compared and analyzed.O-SOFCs can achieve efficient and synergistic ammonia cracking and electrochemical reactions under high-temperature conditions,but material constraints under such conditions limit their development.H-SOFCs demonstrate promising efficiency,yet face challenges including poor stability of electrolyte materials,weak nitridation resistance of the anode,and low efficiency of ammonia decomposition at lower temperatures.关键词
氨燃料/固体氧化物燃料电池/电解质/电池性能/阳极氮化/氢能载体/零碳燃料Key words
ammonia fuel/solid oxide fuel cell/electrolyte/cell performance/anode nitridation/hydrogen energy carrier/zero-carbon fuel分类
能源科技引用本文复制引用
明传旺,赵宇豪,吕友军,李一航..氨基固体氧化物燃料电池的研究进展与机遇[J].综合智慧能源,2025,47(10):10-25,16.基金项目
国家重点研发计划项目(2024YFF0506300) (2024YFF0506300)
陕西省重点研发计划项目(2024CY2-GJHX-66) National Key Research and Development Program of China(2024YFF0506300) (2024CY2-GJHX-66)
Key Research and Development Program of Shaanxi(2024CY2-GJHX-66) (2024CY2-GJHX-66)