分析测试学报2025，Vol.44Issue(11)：2245-2255,11.DOI:10.12452/j.fxcsxb.24122225
黄绍京《大爷》油画微样品综合分析研究
Comprehensive Analytical Study on Micro-samples of Huang Shaojing's Oil Painting"Grandfather"
摘要
Abstract
Oil painting is a key medium in contemporary Chinese art,with complex materials that are prone to aging,and many kinds of diseases.The introduction of modern synthetic materials in the 20th century has significantly impacted these works.This study focuses on Huang Shaojing's repre-sentative work of early realism"Grandfather",which is in the collection of the Anhui Museum,it employs employing a range of scientific analysis methods,including stereomicroscopy,scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS),infrared spectroscopy(FT-IR),X-ray diffraction microanalysis(μ-XRD),micro-Raman spectroscopy(μ-Raman),pyrolysis/gas chromatography-mass spectrometry(Py/GC-MS),and thermally assisted hydrolysis and methylation/gas chromatography-mass spectrometry(THM-Py/GC-MS)to study the structure and material composi-tion of micro-samples from the painting.The results show that the selected micro-sample analysis techniques can effectively and maximally uncover the latent information contained within the sam-ples.The study shows that the oil painting sample consists of four layers:the ground layer uses zinc white as the inorganic filler;the underpainting and pigment layers contain synthetic organic pig-ments,with the yellow being Monoazo-PY3 and the blue being Phthalocyanine-PB 15∶6.The bind-ing agents was polyvinyl acetate and linseed oil,and acrylic monomer and styrene were used as the main modified materials,with dibutyl phthalate and diisobutyl phthalate used as plasticizers,polyvi-nyl alcohol serves as a protective colloid and thickener,trimethyl phosphate as an antifoaming agent,and zirconium oxychloride or zirconium oxide as a drier to modify and enhance the overall perfor-mance of the oil painting materials after film formation.The surface varnish layer consists of a hard resin varnish made from rosin dissolved in linseed oil.This research provides a scientific basis for the identification,restoration,and conservation of components(such as pigments,binders,and addi-tives)in modern and contemporary oil paintings.关键词
油画/黄绍京/微区分析/热裂解/气相色谱-质谱联用/综合研究Key words
oil painting/Huang Shaojing/micro-area analysis/Py/GC-MS/comprehensive re-search分类
化学化工引用本文复制引用
郝锌颖,陈彪,孙红燕,佘媛,朱玥玮,王春秀,游莉,马兰,彭安婷,张百忍..黄绍京《大爷》油画微样品综合分析研究[J].分析测试学报,2025,44(11):2245-2255,11.基金项目
国家自然科学基金青年项目(22304170) （22304170）
安徽省自然科学基金青年项目(2208085QB58) （2208085QB58）
安徽省新时代育人质量工程项目(2024jyjxggyjY012,2022szsfkc010,2022jyjxggyj031) （2024jyjxggyjY012,2022szsfkc010,2022jyjxggyj031）
