燃料化学学报2025，Vol.53Issue(11)：1654-1662,9.DOI:10.1016/S1872-5813(25)60575-5
不同晶貌丝光沸石在异戊烯低聚中的应用
The application of mordenite with different crystal morphologies in isoamylene oligomerization
摘要
Abstract
The oligomerization of light olefins is considered a green production technology.Currently,the application of mordenite in isoamylene oligomerization faces two main challenges:low dimerization selectivity and poor stability.In this work,a series of different SiO2/Al2O3 ratio mordenite are synthesized by utilizing hexamethyleneimine(HMI)as the organic structure directing agent,and it turns out that the rod-like zeolite with the ratio of SiO2/Al2O3=14 exhibits the higher dimerization selectivity.The incorporation of TPOAC optimizes the pore structure and acid site distribution of the rod-like zeolite,which enables the samples to not only exhibit a conversion rate of isoamylene over 88.30％within 12 h,while maintaining good dimerization selectivity.These findings provide a promising approach for improving the efficiency and sustainability of olefin oligomerization processes.关键词
丝光沸石/六亚甲基亚胺/晶体形貌/异戊烯低聚Key words
mordenite/hexamethyleneimine/crystal morphology/isoamylene oligomerization分类
石油、天然气工程引用本文复制引用
王子健,李舒婷,郑佳硕,柯明,宋昭峥..不同晶貌丝光沸石在异戊烯低聚中的应用[J].燃料化学学报,2025,53(11):1654-1662,9.基金项目
The project was supported by the National Natural Science Foundation of China(21776505). （21776505）
