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一种双表面活性剂模板体系制备氮掺杂多孔炭纳米棒用于超级电容器电极

庞超然 张淑芬 王添巍 宋财城 林华 颜文进 王鹏 陈龙明 胡瀛心 吕荣文

新型炭材料(中英文)2025,Vol.40Issue(5):1123-1135,13.
新型炭材料(中英文)2025,Vol.40Issue(5):1123-1135,13.DOI:10.1016/S1872-5805(25)61006-7

一种双表面活性剂模板体系制备氮掺杂多孔炭纳米棒用于超级电容器电极

A dual-surfactant template system for fabricating N-doped porous carbon nanorods for use as supercapacitor electrodes

庞超然 1张淑芬 1王添巍 1宋财城 2林华 1颜文进 1王鹏 1陈龙明 1胡瀛心 3吕荣文1

作者信息

  • 1. 大连理工大学 精细化工全国重点实验室,辽宁 大连 116024
  • 2. 中石化(大连)石油化工研究院,辽宁 大连 116045
  • 3. 辽宁石油化工大学,辽宁 抚顺 113001
  • 折叠

摘要

Abstract

The ability to control the preparation of one-dimensional(1D)porous carbon nanorods,especially during rapid polymerization,is key to their practical application.We report a method for synthesizing 1D porous carbon nanorods,characterized by the formation of rod-like mi-celles that are assembled from sodium palmitate and Pluronic F127,facilitated by protonated melamine,and subsequently converted into melamine-based N-doped polymer nanorods which were carbonized to produce the corres-ponding N-doped carbon nanorods.The specific capacitance of the supercapacitor used the as-pre-pared N-doped nanorods as electrode material in a three-electrode system was calculated to be 301.66 F g-1 at a current density of 0.2 A g-1,with an ultra-high specific surface area normalized capacitance of up to 67.07 μF cm-2.The N-doping and their one-dimensionality give the nanorods a low internal resistance and good stability,making them well suited for fundamental studies and practical applications ranging from materials chemistry to electrochemical energy storage.

关键词

炭纳米棒/双表面活性剂体系/协同组装过程/N掺杂/超级电容器

Key words

Carbon nanorods/Dual-surfactant system/Cooperative assembly process/N-doped/Supercapacitors

引用本文复制引用

庞超然,张淑芬,王添巍,宋财城,林华,颜文进,王鹏,陈龙明,胡瀛心,吕荣文..一种双表面活性剂模板体系制备氮掺杂多孔炭纳米棒用于超级电容器电极[J].新型炭材料(中英文),2025,40(5):1123-1135,13.

基金项目

This work is supported by the National Natural Science Foundation of China(22078044 and 22238002),Fundamental Research Funds for the Central Universities(DUT22LAB610),National Key Research and Development Program of China(2022YFB3806500),Fundamental Research Funds for the Central Universities(DUT2022TB10). 国家自然科学基金(22078044和 22238002) (22078044 and 22238002)

中央高校基本科研业务费专项资金(DUT22LAB610) (DUT22LAB610)

国家重点研发计划(2022YFB3806500) (2022YFB3806500)

中央高校基本科研业务费(DUT2022TB10). (DUT2022TB10)

新型炭材料(中英文)

OA北大核心

1007-8827

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