爆炸与冲击2025，Vol.45Issue(11)：86-97,12.DOI:10.11883/bzycj-2024-0434
NiP@Fe-SBA-15抑爆剂的制备及对PP粉尘爆燃火焰的抑制机理
Preparation of NiP@Fe-SBA-15 suppressant and its inhibition mechanism on polypropylene dust deflagration flames
摘要
Abstract
Polypropylene(PP)is widely utilized in industrial production,yet PP dust generated during its production and transportation can form explosive dust clouds,leading to severe dust explosion accidents that threaten personnel and equipment safety.To address this issue,a novel explosion suppressant,NiP@Fe-SBA-15,was synthesized to inhibit the propagation of PP dust combustion flames.The synthesis involved modifying SBA-15 mesoporous silica with Fe ions and subsequently loading NiP,resulting in a composite powder with uniformly dispersed active components and a well-preserved mesoporous structure.Characterization via SEM-Mapping and N2 adsorption-desorption experiments revealed that NiP@Fe-SBA-15 maintains a high specific surface area,exhibits a regulated pore structure,and shows no significant particle agglomeration.The Hartman tube explosive testing system was employed to evaluate the effect of NiP@Fe-SBA-15 on PP dust deflagration.Results indicated that as the NiP@Fe-SBA-15 additive increased,the flame propagation speed,brightness,and flame length of PP deflagration decreased significantly,with flame propagation almost completely inhibited by a suppressant dosage with the mass fraction of 70%.The dual explosion suppression mechanism of NiP@Fe-SBA-15 was analyzed.Physically,NiP@Fe-SBA-15 occupies reaction space,reducing oxygen and combustible volatile concentrations,while the SBA-15 molecular sieve,exposed by thermal decomposition of the suppressant,absorbs heat and forms a physical barrier,thereby reducing combustion intensity.Chemically,NiP decomposition releases Ni·and P·radicals that consume key free radicals(H·,O·,OH·)in combustion reactions,interrupting explosion chain reactions.Meanwhile,Fe-based species rapidly oxidize to Fe3O4,reducing oxygen availability and further weakening combustion intensity.In summary,NiP@Fe-SBA-15 was proven to be an effective explosion suppressant for PP dust explosions,reducing combustion intensity through combined physicochemical synergies.This research provides a new approach to enhancing polypropylene industry safety.Future work will focus on optimizing the industrial application of NiP@Fe-SBA-15 explosion suppressants while addressing cost,environmental sustainability,and stability issues to further advance dust explosion prevention technology.关键词
聚丙烯粉尘/NiP@Fe-SBA-15/原位合成/抑爆机理Key words
polypropylene dust/NiP@Fe-SBA-15/in situ synthesis/explosion suppression mechanism分类
力学引用本文复制引用
王菲,韩金,陈金射,陈海燕,张延松,羊阳,张阳,朱玉镇..NiP@Fe-SBA-15抑爆剂的制备及对PP粉尘爆燃火焰的抑制机理[J].爆炸与冲击,2025,45(11):86-97,12.基金项目
国家自然科学基金(52374215,51974179) （52374215,51974179）
