重庆科技大学学报(自然科学版)2025,Vol.27Issue(5):43-49,7.DOI:10.19406/j.issn.2097-4531.2025.05.006
气体水合物快速成核生长强化方法研究进展
Research Progress on Enhanced Methods for Rapid Nucleation and Growth of Gas Hydrates
摘要
Abstract
Under the current energy structure transformation and the"Dual Carbon"strategy in our country,gas hy-drate technology holds significant potential for application in the field of carbon capture and storage.The stochastic nature of hydrate nucleation results in long induction periods and slow growth kinetics,while conventional mechani-cal intensification methods cannot satisfy the requirements for large-scale industrial application.To address this problem,researchers have proposed a series of new methods for strengthening the rapid nucleation and growth of gas hydrates.Physical strengthening methods can continuously renew the gas-liquid interface state by applying external disturbances,thereby enhancing the nucleation of hydrates;chemical additive strengthening methods can alter the properties of the solution,reducing the randomness of hydrate nucleation;material strengthening method primarily leverages the large specific surface area and good thermal conductivity of the materials themselves to promote hy-drate nucleation;and the metal corrosion enhancement method facilitates the instantaneous nucleation of hydrates by providing abundant heterogeneous nucleation sites,which result from the synergistic effect of the solid-liquid-gas triphase interface and the high density of hydrogen micro-bubbles formed during the corrosion process.关键词
气体水合物/成核生长/碳捕集与封存/物理强化/化学添加剂强化/材料强化Key words
gas hydrate/nucleation and growth/carbon capture and storage/physical strengthening/chemical-ad-ditive strengthening/material strengthening引用本文复制引用
孟宇航,李政,朱文学..气体水合物快速成核生长强化方法研究进展[J].重庆科技大学学报(自然科学版),2025,27(5):43-49,7.基金项目
重庆市自然科学基金面上项目"氨基酸类促进剂调控环戊烷水合物成核生长动力学及其多尺度结构演变机制"(CSTB2025NSCQ-GPX0205) (CSTB2025NSCQ-GPX0205)
重庆科技大学科研资助项目"垃圾渗滤液作用下水合物生成的热力学特性及动力学反应机理"(CKRC2021008) (CKRC2021008)
重庆科技大学硕士研究生创新计划项目"氨基酸类促进剂强化CO2水合物生成动力学的实验研究"(YKJCX2420335) (YKJCX2420335)