ZnO/FeSiAl导热吸波硅橡胶的制备及其性能OA
Preparation and performance of ZnO/FeSiAl thermal conductive and wave-absorbing silicone rubber
为使材料具有良好的散热及电磁波吸收性能,采用ZnO、片状FeSiAl为功能填料,填充室温硫化硅橡胶,制备了导热吸波复合材料.通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)、万能拉伸实验、导热性能测试以及电磁参数测试分析ZnO/FeSiAl导热吸波硅橡胶的微观形貌、力学特性以及导热和吸波性能.结果表明,共混的ZnO与FeSiAl较为纯净,没有其他杂质,当FeSiAl与ZnO配比为5∶3时两种填料在硅橡胶中的分布最均匀;力学性能方面,随着配比的增加其拉伸强度降低而邵氏硬度却增加;导热性则在配比增加到5∶3时达到最好,热导率为0.85 W/(m·K);同时,在配比为5∶3条件下材料也表现出更好的微波吸收性能;样品厚度为2.0 mm时,在10.87 GHz处的最小反射损耗RLmin为-22.45 dB,有效吸收带宽为4.1 GHz;此外,与周期性频率选择表面(FSS)结合后,吸波性能得到了极大的增强,在10.73 GHz时,实现了最小反射损耗值-59.92 dB.这项工作有助于解决电子设备的热传导和电磁污染的问题.
In order to achieve good heat dissipation and electromagnetic wave absorption per-formance of the material,ZnO and flake FeSiAl were used as functional fillers,and room tem-perature vulcanized silicone rubber was filled to prepare a thermal conductive absorbing compos-ite material.The microstructure,mechanical properties,thermal conductivity and microwave ab-sorption performance of ZnO/FeSiAl thermally conductive and microwave absorbing silicone rubber were analyzed by X-ray diffraction(XRD),scanning electron microscopy(SEM),univer-sal tensile test,thermal conductivity test and electromagnetic parameter test.The results show that the mixed ZnO and FeSiAl are relatively pure and free of other impurities.When the ratio is 5∶3,the distribution of FeSiAl and ZnO in silicone rubber is the most uniform.In terms of me-chanical properties,the tensile strength decreases while the Shore hardness increases with the in-crease of the ratio.The thermal conductivity reaches the best performance when the ratio increa-ses to 5∶3,with a thermal conductivity of 0.85 W/(m·K).At the same time,under the con-dition of a ratio of 5∶3,the material also shows better microwave absorption performance.When the sample thickness is 2.0 mm,the minimum reflection loss RLmin at 10.87 GHz is-22.45 dB,and the effective absorption bandwidth is 4.1 GHz.In addition,after combining with the periodic frequency selective surface(FSS),the microwave absorption performance is greatly enhanced,and the minimum reflection loss value of-59.92 dB is achieved at 10.73 GHz.This work is helpful to solve the problems of heat conduction and electromagnetic pollu-tion in electronic devices.
刘毅;张鸿宇;刘一璇
西安工程大学材料工程学院,陕西西安 710048西安工程大学材料工程学院,陕西西安 710048西安工程大学材料工程学院,陕西西安 710048
ZnO/FeSiAl硅橡胶导热性能吸波性能反射损耗频率选择表面衰减常数
ZnO/FeSiAl silicone rubbersthermal conductivityabsorption performancereflec-tion lossfrequency selective surface(FSS)attenuation constant
《纺织高校基础科学学报》 2025 (5)
45-52,8
陕西省教育厅科学研究计划重点项目(24JR068)陕西省秦创原"科学家+工程师"队伍项目(2025QCY-KXJ-193)
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