纺织高校基础科学学报2025，Vol.38Issue(5)：53-59,7.DOI:10.13338/j.issn.1006-8341.2025.05.007
埃洛石纳米管改性碳泡沫复合材料的性能研究
Properties of HNTs modified carbon foam composites
摘要
Abstract
To optimize carbon foam composite properties,this study synthesized Halloysite Nano-tubes(HNTs)-modified carbon foams via one-step high-temperature carbonization,using zirconi-um-modified phenolic resin as precursor,closed-cell hollow microspheres as dispersed phase,and HNTs as reinforcing phase.The effects of HNTs content(0～8％)on the foam's compressive properties and high-temperature ablation resistance were systematically studied.Results showed that increasing HNTs content improved the modified foam's mechanical properties.Specifically,the foam with 6％HNTs achieved a compressive strength of 13.4 MPa,an 81.1％increase over pure carbon foam(7.4 MPa).It was attributed to effective interfacial bonding between dispersed HNTs and the carbon matrix,as well as synergistic reinforcement by HNTs and hollow micro-spheres to inhibit crack propagation.The modified foams also exhibited excellent high-tempera-ture ablation resistance.After 240 s of ablation,in-situ generated surface ceramic phases(e.g.,SiO2)provided a significant thermal barrier effect,delaying thermal oxidative spallation and crea-ting a temperature difference of over 700 ℃ between the ablated and back surfaces.The introduc-tion of HNTs with varying contents,improved the mechanical properties and anti-ablation stabili-ty of carbon foam composites,providing potential value for the development of aerospace thermal protection materials.关键词
碳泡沫/埃洛石纳米管/压缩性能/耐高温烧蚀Key words
carbon foam/halloysite nanotubes/compressive property/high-temperature ablation resistance引用本文复制引用
王斌,赵伟江,薛功飞,吴谋湖,钟浩祥..埃洛石纳米管改性碳泡沫复合材料的性能研究[J].纺织高校基础科学学报,2025,38(5):53-59,7.基金项目
陕西省科技厅重点研发计划项目(2024NC-YBXM-247) （2024NC-YBXM-247）
西安工程大学研究生创新基金(chx2025040) （chx2025040）
功能性纺织材料及制品教育部重点实验室开放课题(2024FTMP024) （2024FTMP024）
