复合材料科学与工程Issue(10):13-21,9.DOI:10.19936/j.cnki.2096-8000.20251028.003
含功能性基团MOFs在液相吸附的应用及复合智能基材的应用展望
The application prospects of MOFs containing functional groups in liquid-phase adsorption and the application prospects of the composite of MOFs containing functional groups and smart substrates
摘要
Abstract
In recent years,the adsorption of impurities in liquid-phase systems has received increasing attention due to prominent environmental and other issues.Since the adsorbents in liquid-phase adsorption,whether ions or molecules,all have their own characteristics,targeted adsorbents are required for the adsorption of different types of adsorbents.Metal-organic framework materials(MOFs)are widely used due to their good specific surface area and abundant reaction sites.Further,MOFs with functional groups can be more specifically customized for adsorbents with their own characteristics.That is,such MOFs containing functional groups can often become targeted adsor-bents,enabling high efficiency and low cost.This article focuses on MOFs containing functional groups,comprehen-sively summarizes the approaches for introducing functional groups,as well as the ways in which different types of groups achieve targeted adsorption of adsorbates.Finally,the selection strategies of MOFs and adsorbents containing functional groups were proposed.This strategy enables the structural analysis of specific adsorbates,thereby guiding the selection of MOFs with appropriate functional groups for adsorption.However,the inherent powder form of MOFs limits their applications,compositing them with suitable smart substrates can overcome this limitation.In the future,MOFs/smart substrate composites have significant development potential.关键词
功能性基团/液相吸附/针对性/选择策略/金属有机框架材料/智能基材/复合材料Key words
functional gene/liquid-phase adsorption/pertinence/selection strategy/MOFs/smart substrate/composites分类
通用工业技术引用本文复制引用
苏宇杏,兰鑫,张大伟..含功能性基团MOFs在液相吸附的应用及复合智能基材的应用展望[J].复合材料科学与工程,2025,(10):13-21,9.基金项目
特种环境复合材料技术国家级重点实验室基金(6142905232908) (6142905232908)