含能材料2025，Vol.33Issue(11)：1341-1353,13.DOI:10.11943/CJEM2025016
第三代含能材料热性能与燃烧反应研究进展
Advance of Thermal Decomposition and Combustion Reaction of Third-generation Energetic Materials
摘要
Abstract
The combustion process of energetic materials(EMs)is a complex multi-stage process.By studying their thermal de-composition and combustion reactions,establishing precise combustion reaction kinetics models enables effective prediction of the thermal behavior of EMs,which is of significant importance for their synthesis,production,transportation,storage,and practical application in modern weaponry and equipment.Compared to traditional EMs,third-generation EMs exhibit higher en-ergy density,which imposes more stringent requirements on their thermal stability.This review summarizes recent advances in thermal properties and combustion research of third-generation EMs,including both ionic and covalent types.The current re-search status on thermal properties and combustion reactions of typical third-generation EMs is expounded from three perspec-tives:thermal decomposition profiles,decomposition pathways/mechanism,and combustion performance.It identifies the short-comings of the current research and proposes the research direction of the thermal behavior of the third-generation energetic ma-terials.It is proposed to construct a multi-scale coupled research system:high-precision measurement of combustion parameters via novel experimental apparatus,accurate diagnosis of combustion intermediates,and cross-scale modeling combining quan-tum chemistry-machine learning-fluid mechanics to achieve full-chain analysis from free-radical mechanisms to macroscopic flame propagation.关键词
第三代含能材料/燃烧/热分解Key words
third-generation energetic/combustion/thermal decomposition分类
武器工业引用本文复制引用
刘丁,张言,牛诗尧,赵凤起,李思恒,董英楠,曲文刚..第三代含能材料热性能与燃烧反应研究进展[J].含能材料,2025,33(11):1341-1353,13.基金项目
国家自然科学基金(22175140) National Natural Science Foundation of China(No.22175140) （22175140）
