华侨大学学报（自然科学版）2025，Vol.46Issue(6)：666-674,9.DOI:10.11830/ISSN.1000-5013.202509009
电子回流阻挡层提升钙钛矿太阳能电池的光电性能
Electronic Reflux Barrier Layer for Improving Photoelectric Performance of Perovskite Solar Cells
摘要
Abstract
Using the spin-coating method,1-amantadine hydrochloride(ADA)was introduced as an interface modifier between tin dioxide(SnO2)and perovskite layers to form an electron reflow barrier layer,which served to passivate interface defects,prevent electron reflow,and suppress non-radiative recombination at the interface,and could also enhance the photoelectric performance of perovskite solar cells.The results showed that the amino lone pair electrons in ADA could coordinate with uncoordinated Pb2+,which was conducive to the formation of high-quality perovskite films,reducing defect density and increasing open-circuit voltage.The optimal power conversion efficiency(PCE)of the perovskite solar cells modified by ADA reached 23.07％,the open-circuit voltage was 1.13 V,the short-circuit current density was 24.67 mA·cm-2,and the fill factor was 82.59％.After being stored in an air environment for 1 000 h,the modified device still maintained a PCE of over 85％,and both efficiency and stability were significantly enhanced.关键词
钙钛矿太阳能电池/界面工程/缺陷钝化/电子回流Key words
perovskite solar cells/interface engineering/defect passivation/electron reflux分类
信息技术与安全科学引用本文复制引用
高林,田景旭,崔鏸元,吴季怀,兰章,李立清,杜振波,田志飞..电子回流阻挡层提升钙钛矿太阳能电池的光电性能[J].华侨大学学报（自然科学版）,2025,46(6):666-674,9.基金项目
国家自然科学基金资助项目(51972123,52372190) （51972123,52372190）
福建省自然科学基金资助项目(2023J01116) （2023J01116）
环境友好功能材料教育部工程研究中心资助项目(51101,5032502) （51101,5032502）
