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共价有机框架中的组分工程用于定制光催化

Yihong Shao Rongchen Shen Song Wang Shijie Li Peng Zhang Xin Li

物理化学学报2025，Vol.41Issue(12)：1-48,48.

物理化学学报2025，Vol.41Issue(12)：1-48,48.DOI:10.1016/j.actphy.2025.100176

共价有机框架中的组分工程用于定制光催化

Composition engineering in covalent organic frameworks for tailored photocatalysis

Yihong Shao ¹Rongchen Shen ¹Song Wang ²Shijie Li ³Peng Zhang ⁴Xin Li¹

作者信息

1. Institute of Biomass Engineering,Key Laboratory for Biobased Materials and Energy of Ministry of Education,College of Materials and Energy,South China Agricultural University,Guangzhou 510642,Guangdong Province,China
2. Hubei Key Lab Low Dimens Optoelect Mat&Devices,Hubei University of Arts and Science,Xiangyang 441053,Hubei Province,China
3. Key Laboratory of Health Risk Factors for Seafood of Zhejiang Province,National Engineering Research Center for Marine Aquaculture,College of Marine Science and Technology,Zhejiang Ocean University,Zhoushan 316022,Zhejiang Province,China
4. State Centre for International Cooperation on Designer Low-Carbon&Environmental Materials(CDLCEM),School of Materials Science and Engineering,Zhengzhou University,Henan,Zhengzhou 450001,Henan Province,China
折叠

摘要

Abstract

The harmful effects of the energy crisis and environmental degradation are becoming increasingly severe,which urgently demands the advancement of eco-friendly and sustainable production techniques.Direct conversion of abundant solar energy into chemical energy represents a promising green and efficient technological solution.In this process,photocatalysts play a pivotal role.Covalent organic frameworks(COFs),a class of porous materials interconnected by covalent bonds,exhibit exceptional potential for photocatalysis due to their high surface area,excellent crystallinity,and tunable structures.This review discusses the roles of compositional regulation in enhancing the photocatalytic performance of COFs,including modulating light absorption,increasing active sites,promoting exciton dissociation,and improving carrier separation.Furthermore,computational and mechanistic characterization methods are also discussed.More importantly,the key strategies in compositional regulation,such as heteroatom engineering,metal single-atom engineering,ion engineering,functional group engineering,Donor-Acceptor(D-A)molecular engineering,side chain engineering,multi-component engineering,isomerism engineering,conjugate bridge engineering,single-molecule junction engineering,and interlayer engineering,are carefully summarized.Moreover,their diversified modification strategies and applications in photocatalytic hydrogen(H2)evolution,hydrogen peroxide(H2O2)production,and carbon dioxide(CO2)reduction are also addressed.Finally,the current challenges and future opportunities for COF-based photocatalysis are outlined.

关键词

共价有机框架/组分调控/光催化应用/工程和改性策略/激子解离

Key words

Covalent organic frameworks/Compositional regulation/Photocatalytic applications/Engineering and modification strategies/Exciton dissociation

分类

化学化工

引用本文复制引用

Yihong Shao,Rongchen Shen,Song Wang,Shijie Li,Peng Zhang,Xin Li..共价有机框架中的组分工程用于定制光催化[J].物理化学学报,2025,41(12):1-48,48.

基金项目

X.Li thanks the National Natural Science Foundation of China(22378148,21975084)and the Natural Science Foundation of Guangdong Province(2024A1515012433)for their support.R.Shen thanks the National Natural Science Foundation of China(2230082074). X.Li感谢国家自然科学基金(22378148,21975084)和广东省自然科学基金(2024A1515012433)的支持.R.Shen感谢国家自然科学基金(2230082074)的资助（22378148,21975084）

物理化学学报

OA北大核心

ISSN：1000-6818

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