新型炭材料（中英文）2025，Vol.40Issue(6)：1246-1264,19.DOI:10.1016/S1872-5805(25)61022-5
低温钠离子电池中硬炭负极性能的提高策略
A review of ways to improve the performance of hard carbon anodes in low-temperature sodium-ion batteries
摘要
Abstract
Because of their excellent low-temperature(-15 to-40 ℃)tolerance,sodium-ion batteries are emerging as a complement to lithium-ion batteries for use in extremely cold environments(e.g.high-latitude areas).Hard carbon has a high low-voltage sodium stor-age capacity and a good initial efficiency,making it one of the most promising anode materials for sodium-ion batteries.It has a complex structure,featuring closed pores,nano graphitic domains,and surface functional groups.The sodium storage sites in hard carbon are re-viewed as are the widely accepted sodium storage mechanisms.The main factors contributing to the de-gradation of the good low-temperature performance in hard carbon anodes are considered,including sodium dendrite formation,low ion diffusion rates,and surface-side reactions.Fi-nally,strategies to increase the low-temperature sodium storage performance of hard carbon anodes are summarized,including bulk structure design,and improvements in interfaces and cut-off voltage.Guidance is provided for improving the low-temper-ature performance of hard carbon anodes to accelerate the development of these batteries.关键词
炭材料/钠离子电池/负极材料/低温/结构优化Key words
Carbon materials/Sodium-ion batteries/Anode materials/Low-temperature/Structure design分类
化学化工引用本文复制引用
CUI Zhe,SHI Li-luo,JU Zhi-cheng,CHEN Ya-xin,LI Bing-yu,XIONG Hang,LI Tian,XIE Ming-xin,HU Jing-ying,QIU Xia,GUI Zhu-qin,ZHOU Rui..低温钠离子电池中硬炭负极性能的提高策略[J].新型炭材料（中英文）,2025,40(6):1246-1264,19.基金项目
The authors appreciate the support from Nation-al Natural Science Foundation of China(22279162,52402069),the Natural Science Foundation of Ji-angsu Province(Youth Fund,No.BK20221138,BK20240333),and the College Students'Innovative Entrepreneurial Training Plan Program of China Uni-versity of Mining and Technology(202410290234Y). 国家自然基金(22279162,52402069) （22279162,52402069）
江苏省自然科学基金(Youth Fund,No.BK20221138,BK20240333) （Youth Fund,No.BK20221138,BK20240333）
中国矿业大学大学生创新创业训练计划项目(202410290234Y). （202410290234Y）
