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流动电极电容去离子去除铜离子的性能与系统污染研究

杨晨旭 余铭浩 陈梦 马俊俊 牛建瑞 张静 刘春 陈晓轩

河北科技大学学报2025,Vol.46Issue(6):704-712,9.
河北科技大学学报2025,Vol.46Issue(6):704-712,9.DOI:10.7535/hbkd.2025yx06012

流动电极电容去离子去除铜离子的性能与系统污染研究

Study on the performance and system pollution of copper ion removal by flow electrode capacitive deionization

杨晨旭 1余铭浩 1陈梦 1马俊俊 1牛建瑞 1张静 1刘春 1陈晓轩1

作者信息

  • 1. 河北科技大学环境科学与工程学院,河北 石家庄 050018||河北省污染防治生物技术实验室,河北 石家庄 050018
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摘要

Abstract

In order to address the issue of system contamination caused by the treatment of copper ions(Cu2+)wastewater using electrochemical technology,which leads to poor system stability,this paper focused on the pollution characteristics of the system during the removal of Cu2+by flow electrode capacitive deionization(FCDI),and explored the influence mechanism of key parameters such as applied voltage,inlet Cu2+concentration,flow electrode velocity,and inlet water quality on the Cu2+removal performance of the system.The results show that under the conditions of an applied voltage of 0.8 V,an influent Cu2+concentration of 50 mg/L,and a flowing electrode flow rate of 1.2 mL/min,the Cu2+removal rate reaches 56.22%,the charge efficiency is 90%,and the copper removal rate is 0.03 μmol/(cm2·min).At the same time,the continuous operation stability of the flow electrode system under different cycling modes is investigated,and the pollution characteristics of the ion exchange membrane and activated carbon electrode are analyzed.The results indicate that the flow electrode exhibits significant advantages in copper ion removal under the single cycle(SC)mode,and the membrane and electrode exhibit the lowest level of pollution.This study provides important reference for the application of FCDI technology in heavy metal removal.

关键词

环境工程学其他学科/含铜废水/FCDI/铜离子去除/电极污染/膜污染

Key words

other disciplines of environmental engineering/copper wastewater/FCDI/copper ion removal/electrode fouling/membrane fouling

分类

海洋科学

引用本文复制引用

杨晨旭,余铭浩,陈梦,马俊俊,牛建瑞,张静,刘春,陈晓轩..流动电极电容去离子去除铜离子的性能与系统污染研究[J].河北科技大学学报,2025,46(6):704-712,9.

基金项目

国家自然科学基金(52300006) (52300006)

中央引导地方科技发展资金项目(236Z3811G) (236Z3811G)

河北科技大学学报

OA北大核心

1008-1542

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