燃料化学学报（中英文）2025，Vol.53Issue(12)：1713-1725,13.DOI:10.1016/S1872-5813(25)60553-6
非贵金属催化糠醛及其衍生物加氢转化制高值化学品研究进展
Recent advance in catalytic hydrogenation of furfural and its derivatives to value-added chemicals over non-noble metal catalysts
摘要
Abstract
The increasingly severe environmental and energy challenges are driving the demand to produce chemicals and energy substances from renewable resources.Among industrially produced biomass-derived compounds,furfural is recognized as an important platform molecule.It can be converted into various value-added chemicals such as furan derivatives,diols and carboxylic acids-via catalytic hydrogenation,hydrogenolysis,and oxidation.Selective activation of C=C,C=O and C-O bonds during the hydrogenation of furfural and its derivatives represents a primary pathway for furfural valorization.However,achieving selective scission of these bonds using non-noble metal catalysts under mild reaction conditions remains challenging.This review summarizes recent advances in using non-noble metal catalysts(Cu-,Ni-,and Co-based catalysts)for the catalytic hydrogenation of furfural and its derivatives to produce furfuryl alcohol,2-methylfuran,1,5-pentanediol,and 1,2-pentanediol.Some strategies such as fabricating bimetallic sites,metal-oxide interfaces,and metal-acid sites enable selective activation of specific chemical bonds.Nevertheless,the understanding of the dynamic catalytic processes at active centers under real reaction conditions remains insufficient.Advanced operando characterization techniques can provide deep insights into the dynamic evolution of active sites during reactions,helping to clarify the deactivation mechanisms of non-noble metal catalysts.The non-noble metal catalysts show great potential for the large-scale,high-value conversion of furfural and its derivatives,making this field a key focus for future biomass catalytic processes.关键词
糠醛/糠醇/2-甲基呋喃/戊二醇/催化加氢Key words
furfural/furfuryl alcohol/2-methylfuran/pentanediol/catalytic hydrogenation分类
化学化工引用本文复制引用
王月清,申伟杰,董李,丁国强,朱玉雷..非贵金属催化糠醛及其衍生物加氢转化制高值化学品研究进展[J].燃料化学学报（中英文）,2025,53(12):1713-1725,13.基金项目
The project was supported by Shanxi Provincial Natural Science Foundation of China(202403021221127).山西省自然科学基金(202403021221127)资助 （202403021221127）
