燃料化学学报(中英文)2025,Vol.53Issue(12):1739-1757,19.DOI:10.1016/S1872-5813(25)60589-5
城市固体废物制备绿色甲醇进展
Progress in green methanol synthesis from municipal solid wastes
摘要
Abstract
The mass generation of municipal solid waste(MSW)poses a serious challenge to the ecological environment and remains a critical problem worldwide.Methanol is an important raw material of modern industry which also serves as clean fuel to transportation,energy storage,etc.The production of methanol by using MSW as feedstock not only mitigates environmental challenges but also provides a renewable source,offering substantial environmental and economic benefits.This work focuses on the progress of the MSW-to-methanol processes.Firstly,the conversion routes of MSW-to-methanol including pyrolysis,gasification,anaerobic digestion and electrolysis are reviewed from the perspective of the technology maturity and economics.Among these routes,the methanol synthesis based on MSW gasification is the main pathway owing to the technological maturity and economic feasibility.Therefore,the second section focuses on the MSW gasification and optimization of syngas quality.Thirdly,the catalysts adopted in the methanol synthesis have been evaluated.Finally,the progress of the industrialization of MSW-to-methanol is reviewed.The prospects will be closely related to the one-step preparation of high-quality syngas,synergistic conversion of syngas with extra H2 sources and the optimization of low-temperature catalysts for methanol synthesis.关键词
城市固体废物/甲醇/气化/合成气调整/Cu/ZnO催化剂Key words
MSW/methanol/gasification/syngas conditioning/Cu/ZnO catalyst分类
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李明,陈德珍,钱柯贞,胡雨燕..城市固体废物制备绿色甲醇进展[J].燃料化学学报(中英文),2025,53(12):1739-1757,19.基金项目
The project was supported by Shanghai Municipal Science and Technology Commission's Carbon Peak and Carbon Neutrality Special Project(22dz1208200),Opening Foundation of Shanghai Solid Waste Treatment and Recycling Engineering Research Center(2021GFZX008).上海市科学技术委员会碳达峰碳中和专项项目(22dz1208200)和上海市固体废物处理与回收工程研究中心开放基金(2021GFZX008)资助 (22dz1208200)