安全、健康和环境2025，Vol.25Issue(12)：53-57,5.DOI:10.3969/j.issn.1672-7932.2025.12.008
长链烷醇类工业废水处理研究
Study on the Treatment of Long-Chain Alkanol Industrial Wastewater
Meng Xiantan 1Zhang Fangyin 1Liang Ming1
作者信息
- 1. Research Institute of Qilu Branch Co.,SINOPEC,Shandong,Zibo,255400
- 折叠
摘要
Abstract
This study addresses the challenge of treating refractory industrial wastewater containing long-chain alkanols,characterized by high biotoxicity,relative nutrient deficiency,and poor biodegradability,mak-ing it difficult to undergo biochemical treatment.Based on an exploration of the mechanism of UV photocatalytic oxidation for treating such wastewater,this study explored the feasibility and optimized the process of a medium-pressure UV process employing a hydrogen peroxide/iron salt system to treat tert-butanol(TBA)wastewater.The effects of reaction time,catalyst dosage,and oxidant dosage on Chemical Oxygen Demand(COD)removal efficiency were compared.Optimal operating conditions were determined,achieving COD reduction from over 2×104 mg/L to below 60 mg/L.This treatment meets the influent requirements for subsequent biological treat-ment facilities,demonstrating the advantages of this process:environmental friendliness,operational simplicity,high treatment efficiency,and low capital and operating costs.Building upon these results,direct investment and operational cost estimates were calculated.A wastewater treatment facility for 10 t/d of tert-butanol-contai-ning wastewater is projected to require approximately 200×104 yuan in direct investment,with a treatment cost of about 200 yuan per ton of wastewater.This work lays a foundation for subsequent scale-up applications.关键词
叔丁醇/废水/紫外光/催化氧化/CODKey words
tert-butanol/wastewater/UV/catalytic oxidation/COD分类
资源环境引用本文复制引用
Meng Xiantan,Zhang Fangyin,Liang Ming..长链烷醇类工业废水处理研究[J].安全、健康和环境,2025,25(12):53-57,5.
