有色金属科学与工程2025，Vol.16Issue(6)：848-856,9.DOI:10.13264/j.cnki.ysjskx.2025.06.002
AgIn5S8/BiOCl复合光催化剂的制备及其增强抗生素去除性能研究
Preparation of AgIn5S8/BiOCl composite photocatalysts and study on their enhanced antibiotic removal performance
摘要
Abstract
BiOCl is one of the highly promising photocatalysts,but due to its wide bandgap,its solar energy utilization efficiency is low,thereby limiting its photocatalytic performance.In this paper,a series of flower-shaped AgIn5S8/BiOCl heterojunction composite catalysts was prepared using a simple solution chemistry method to promote the separation and transfer of photo-generated electrons and holes,effectively extending their light response range into visible light.The photocatalytic degradation effect of the prepared catalysts for tetracycline hydrochloride(TC)under visible light conditions was studied.The optimized sample BOAg-3,prepared with a loading of 0.03 g of AgIn5S8,showed a photocatalytic degradation rate of 0.011 9 min-1 for TC,2.20 and 1.78 times higher than that of BiOCl and AgIn5S8,respectively.The composition,structure,and photoelectrochemical properties of AgIn5S8/BiOCl heterojunction photocatalysts were analyzed by various characterization methods(XRD,SEM,PL,etc.),and it is proposed that the separation and transfer of photogenerated electrons and holes at the AgIn5S8/BiOCl heterojunction interface is an S-Scheme heterojunction mechanism.In addition,it was found through capture agent experiments that the main active species in the photocatalytic degradation process are superoxide radicals(·O2-).关键词
光催化降解/BiOCl/AgIn5S8/异质结/盐酸四环素Key words
photocatalytic degradation/BiOCl/AgIn5S8/heterojunction/tetracycline hydrochloride分类
矿业与冶金引用本文复制引用
ZHU Hanfeng,CHEN Wenqi,YU Changbin,LEI Qiong,HUANG Weiya..AgIn5S8/BiOCl复合光催化剂的制备及其增强抗生素去除性能研究[J].有色金属科学与工程,2025,16(6):848-856,9.基金项目
国家自然科学基金资助项目(52360005,22366018) （52360005,22366018）
