广西民族大学学报(自然科学版)2025,Vol.31Issue(4):22-28,106,8.
河北行唐故郡遗址车马坑出土糟朽漆膜研究
Research on the Deteriorated Lacquer Film Unearthed from the Chariot and Horse Pit at the Gujun Site in Xingtang,Hebei Province
摘要
Abstract
The lacquered chariots unearthed from the Gujun site in Xingtang,Hebei Province,provide crucialmaterial evidence for studying the chariot system of the Eastern Zhou Dynasty.However,upon excavation,the lacquered carriage bodies had deteriorated into fragile lacquer-soil composites,posing significant conservation challenges.This study focuses on the remains of the lacquer film from Chariot No.3 in Chariot and Horse Pit No.2 and its surrounding burial soil.Techniques such as microscopic observation,scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS),infrared spectroscopy(IR),Raman spectroscopy,dynamic vapor sorption(DVS),X-ray diffraction(XRD),and X-ray fluorescence(XRF)were employed to analyze the preservation state,composition,and environmental stability of the lacquer film,as well as the mineral composition,chemical indicators,and soluble salts of the soil.Results show that the lacquer is urushi,with cinnabar as the red pigment.The lacquer film is severely corroded,exhibiting extensive porosity and long cracks;the white needle-like crystals on its surface are anorthite,and the film's hygroscopicity is as high as 19.5%.The burial soil primarily consists of minerals such as quartz and anorthite,with a pH of 8.3.Soluble salts are mainly NaCl,CaSO₄,and CaCl₂,with a total salt content of approximately 0.17%and a saturated moisture content of 9.51%.This research explores the relationship between the decay state of the lacquer film and soil corrosion,preliminarily elucidates the formation causes of the lacquer-soil composites,and provides important scientific support for the conservation of the lacquered chariots unearthed from the chariot and horse pits at the Gujun site in Xingtang.关键词
行唐故郡遗址/漆膜/土壤腐蚀/可溶盐Key words
Gujun Site in Xingtang/Archaeological lacquer film/Soil corrosion/Soluble salts分类
社会科学引用本文复制引用
陈佳柯,赵子怡,刘勇,韩向娜,龙琛..河北行唐故郡遗址车马坑出土糟朽漆膜研究[J].广西民族大学学报(自然科学版),2025,31(4):22-28,106,8.基金项目
北京市宣传文化高层次人才培养资助项目(99203070) (99203070)
国家社会科学基金重大项目(20&ZD258) (20&ZD258)
中国社会科学院创新工程项目(2021KGYJ022) (2021KGYJ022)
中国社会科学院研究所实验室综合资助项目(2024SYZH002) (2024SYZH002)
中国社会科学院学科建设"登峰战略"资助计划(DF2023TS07). (DF2023TS07)