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双氟磺酰亚胺盐的合成研究进展

胡志林 白瑞兵 谢天昊 郑海鑫

化工进展2025,Vol.44Issue(12):6813-6827,15.
化工进展2025,Vol.44Issue(12):6813-6827,15.DOI:10.16085/j.issn.1000-6613.2024-1806

双氟磺酰亚胺盐的合成研究进展

Research progress on synthesis technology of bis(fluorosulfonyl)imide salts

胡志林 1白瑞兵 2谢天昊 1郑海鑫1

作者信息

  • 1. 龙子湖新能源实验室低碳工业系统中心,河南郑州 450000
  • 2. 龙子湖新能源实验室低碳工业系统中心,河南郑州 450000||平顶山学院化学与环境工程学院,河南平顶山 467000
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摘要

Abstract

Bis(fluorosulfonyl)imide salts(MFSI)are important fluorine-containing compounds.Lithium-ion batteries and sodium-ion batteries with electrolytes containing MFSI as the main salts have demonstrated excellent overall electrochemical performance.With the rapid development of the new energy industry,the synthesis of MFSI has received widespread attention and research.This paper primarily focused on the application of MFSI in the battery field,thoroughly discussed its synthesis process and purification methods,and then briefly introduced the preparation equipment and large-scale production status of lithium bis(fluorosulfonyl)imide(LiFSI).Based on the above analysis,the paper further analyzed the existing problems in MFSI synthesis technology,and proposed that the exploration of the mechanism of the fluorination process of MFSI and the development of a safe and efficient catalytic fluorination process were the main directions for the future research.This article aimed to provide reference for the optimization and upgrade of MFSI synthesis technology,and further promoting the industrialization process of high-performance lithium-ion and sodium-ion batteries.

关键词

双氟磺酰亚胺盐/锂盐/电解质/锂离子电池/新能源

Key words

bis(fluorosulfonyl)imide salts/lithium salts/electrolytes/lithium-ion batteries/new energy

分类

化学化工

引用本文复制引用

胡志林,白瑞兵,谢天昊,郑海鑫..双氟磺酰亚胺盐的合成研究进展[J].化工进展,2025,44(12):6813-6827,15.

基金项目

郑州中科新兴产业技术研究院自筹项目(1101032202). (1101032202)

化工进展

OA北大核心

1000-6613

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