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氰化尾渣中典型硫化矿物的表面特性及其浮选回收研究综述

张裕海 赵前飞 张剑廷 李慧 李俊鹏 郑冰清

矿产保护与利用2025,Vol.45Issue(6):109-122,14.
矿产保护与利用2025,Vol.45Issue(6):109-122,14.DOI:10.13779/j.cnki.issn1001-0076.2025.08.013

氰化尾渣中典型硫化矿物的表面特性及其浮选回收研究综述

Review on Surface Characteristics and Flotation Recovery of Typical Sulfide Minerals in Cyanide Tailings

张裕海 1赵前飞 2张剑廷 1李慧 2李俊鹏 3郑冰清3

作者信息

  • 1. 上海逢石工程技术有限公司,江苏 扬州 225119||难采选铁矿资源高效开发利用技术国家地方联合工程研究中心,辽宁 沈阳 110819
  • 2. 难采选铁矿资源高效开发利用技术国家地方联合工程研究中心,辽宁 沈阳 110819||东北大学 资源与土木工程学院,辽宁 沈阳 110819
  • 3. 上海逢石工程技术有限公司,江苏 扬州 225119
  • 折叠

摘要

Abstract

Cyanide tailings contain substantial amounts of valuable elements such as Cu,Fe,Pb,and Zn,presenting considerable potential for resource utilization.The cyanide leaching of gold ore involves complex physical and chemical interactions that play a key role in the flotation separation of sulfide minerals from cyanide tailings.Firstly,the crystal structure,physico-chemical properties,and flotation behavior of sulfide minerals in the gold ore grinding system are reviewed.Secondly,the mechanism of deep cyanide inhibition at the flotation interface of chalcopyrite,pyrite,galena,and sphalerite in cyanide tailings is discussed.Additionally,the characteristics and practical applications of major decyanation methods used domestically and internationally are summarized.Finally,the process and key factors influencing the flotation recovery of sulfide minerals in industrial applications are reviewed.The type and stability of cyanide at the mineral interface were identified as critical factors influencing the flotation separation efficiency of sulfide minerals.Based on these findings,it is recommended to optimize the physico-chemical properties of sulfide mineral surfaces during grinding,to develop advanced cyanide degradation technologies and reagents,and to improve the selectivity of sulfide mineral flotation.These strategies are essential to maximize the efficient and sustainable utilization of cyanide tailings.

关键词

氰化尾渣/硫化物/浮选分离/界面污染/资源化

Key words

cyanide tailings/sulfide/flotation separation/interface pollution/resource utilization

分类

矿业与冶金

引用本文复制引用

张裕海,赵前飞,张剑廷,李慧,李俊鹏,郑冰清..氰化尾渣中典型硫化矿物的表面特性及其浮选回收研究综述[J].矿产保护与利用,2025,45(6):109-122,14.

基金项目

国家自然科学基金项目(52274256) (52274256)

2024年度国家资助博士后研究人员计划C档(GZC20240228) (GZC20240228)

东北大学博士后基金项目(20240206) (20240206)

中央高校基本科研业务专项资金资助项目(N2401023) (N2401023)

矿产保护与利用

1001-0076

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