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基于煤/焦组成和结构解析的水煤浆成浆性能研究

李雯 钟梅 俞音 代正华 刘洋 靳立军 赵辉 熊赛

燃料化学学报(中英文)2026,Vol.54Issue(1):89-103,15.
燃料化学学报(中英文)2026,Vol.54Issue(1):89-103,15.DOI:10.3724/2097-213X.2025.JFCT.0017

基于煤/焦组成和结构解析的水煤浆成浆性能研究

Study on the slurry forming performance of coal water slurry based on the analysis of coal/coke composition and structure

李雯 1钟梅 1俞音 2代正华 3刘洋 1靳立军 4赵辉 5熊赛6

作者信息

  • 1. 新疆大学化工学院省部共建碳基能源资源化学与利用国家重点实验室新疆煤炭清洁转化与化工过程重点实验室,新疆乌鲁木齐 830017
  • 2. 新疆大学化工学院省部共建碳基能源资源化学与利用国家重点实验室新疆煤炭清洁转化与化工过程重点实验室,新疆乌鲁木齐 830017||自治区生态环境科学研究院,新疆乌鲁木齐 830011
  • 3. 新疆大学化工学院省部共建碳基能源资源化学与利用国家重点实验室新疆煤炭清洁转化与化工过程重点实验室,新疆乌鲁木齐 830017||华东理工大学国家能源煤气化技术研发中心上海煤气化工程技术研究中心,上海 200237
  • 4. 新疆大学化工学院省部共建碳基能源资源化学与利用国家重点实验室新疆煤炭清洁转化与化工过程重点实验室,新疆乌鲁木齐 830017||大连理工大学化工学院精细化工国家重点实验室煤化工研究所,辽宁大连 116024
  • 5. 华东理工大学国家能源煤气化技术研发中心上海煤气化工程技术研究中心,上海 200237
  • 6. 新疆天池能源有限责任公司,新疆昌吉 831500
  • 折叠

摘要

Abstract

Considering that coal quality is a key factor affecting the performance of coal water slurry(CWS),in this research,the composition and structure of five coal samples from the Xinjiang-Zhundong coal B2,B3,B5,Heishan coal(HS),Hongshaquan coal(HSQ)and Naomaohu coke(XTJ)-were analyzed,aiming to investigate the influence mechanisms of single coals and coal/coke blending on slurryability.The results showed that the HS,characterized by the aromatic carbon skeleton dominated by 2-3 rings,exhibited low oxygen content and few hydrophilic phenolic hydroxyl,carbonyl,and carboxyl groups,which contributed to its superior slurry performance compared to other coal samples.Even at a remarkably high slurry concentration of 70.98%,the apparent viscosity remained as low as 858 mPa·s.In contrast,B3 and B5 exhibited poor slurry performance due to their abundant oxygen-containing functional groups and strong hydrophilicity,which reduced free water content in the slurry.Additionally,the high content of adsorbed water indicated a thicker hydration film on coal particle surfaces,hindering dispersant adsorption.The addition of 20%HS/XTJ to B5 disrupted the three-dimensional network structure formed by clustered particles and covered the oxygen-containing functional groups.This process not only released previously encapsulated water but also reduced hydration layer thickness.Consequently,free water content increased within the slurry,enhancing dispersant performance.These effects collectively increased coal slurry concentration by approximately 2.40%(reaching 59.00%),reduced apparent viscosity by~40%,and improved fluidity to an A+rating.

关键词

水煤浆/成浆性/组成结构/流变行为/水分布

Key words

coal water slurry/slurry ability/composition and structure/rheological behavior/water distribution

分类

化学化工

引用本文复制引用

李雯,钟梅,俞音,代正华,刘洋,靳立军,赵辉,熊赛..基于煤/焦组成和结构解析的水煤浆成浆性能研究[J].燃料化学学报(中英文),2026,54(1):89-103,15.

基金项目

Supported by the Key Research and Development Plan of Xinjiang Autonomous Region(2023B01013),the Science and Technology Planning Project in Changji,Xinjiang(2023Z03).新疆自治区重点研发计划项目(2023B01013),新疆昌吉州科技计划项目(2023Z03)资助 (2023B01013)

燃料化学学报(中英文)

2097-213X

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