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冷凝-芬顿氧化联合处理挥发性有机化合物废气

刘松涛 孟子嵛 程媌媌 陈传敏 贾文波 曹悦

化学工程2026,Vol.54Issue(1):1-6,6.
化学工程2026,Vol.54Issue(1):1-6,6.DOI:10.3969/j.issn.1005-9954.2026.01.001

冷凝-芬顿氧化联合处理挥发性有机化合物废气

Combined treatment of VOCs waste gas using condensation-Fenton oxidation

刘松涛 1孟子嵛 1程媌媌 1陈传敏 1贾文波 1曹悦1

作者信息

  • 1. 华北电力大学 河北省燃煤电站烟气多污染物协同控制重点实验室,河北 保定 071003||华北电力大学 区域能源系统优化教育部重点实验室,北京 102206
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摘要

Abstract

VOCs(volatile organic compounds)waste gas was simulated using cooking oil fumes,and the waste gas was treated using a combined condensation-Fenton oxidation process.After gas-liquid separation,the gas was separately treated by the waste gas treatment system and the waste water treatment system.The waste gas,after being condensed,was adsorbed by secondary activated carbon and then discharged.The waste water generated by condensation was first oxidized by Fenton's reagent,and then discharged through a sand filter and activated carbon filtration.The optimal process conditions for both the waste gas treatment system and the waste water treatment system were determined.Under the conditions of an inlet air flow rate of 160 mL/L,a condensation temperature of-10℃,and an inlet air temperature of 150℃,the removal rate of oil fumes after condensation is 87.99%.When the equipment is connected to liquid nitrogen for condensation,the removal rate of oil fumes increases to 97.41%.Under the conditions of pH 3.0,ferrous sulfate dosage of 0.13 g/L,mass fraction 30%hydrogen peroxide dosage of 0.15 mL/L,reaction time of 50 min,PAC(polyaluminium chloride)dosage of 250 mg/L,and PAM(polyacrylamide)dosage of 2 mg/L,the lowest effluent COD(chemical oxygen demand)reaches 42 mg/L,which is lower than the first-class standard for comprehensive wastewater discharge,and the COD removal rate reaches 73.32%.

关键词

挥发性有机化合物/冷凝/芬顿氧化/废气处理

Key words

VOCs/condensation/Fenton oxidation/waste gas treatment

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引用本文复制引用

刘松涛,孟子嵛,程媌媌,陈传敏,贾文波,曹悦..冷凝-芬顿氧化联合处理挥发性有机化合物废气[J].化学工程,2026,54(1):1-6,6.

化学工程

1005-9954

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