中国塑料2026，Vol.40Issue(1)：85-90,6.DOI:10.19491/j.issn.1001-9278.2026.01.012
加成型双组分液体硅橡胶交联硫化反应进程研究
A rheological study on crosslinking kinetics in additively manufactured two-component liquid silicone rubber
赵炳祺 1裴文宇 2初朝阳 1付中禹1
作者信息
- 1. 长春工业大学化学工程学院,长春 130012
- 2. 通榆县第九中学,吉林 白城 137200
- 折叠
摘要
Abstract
This study systematically investigated the crosslinking kinetics of additively manufactured two-component liq-uid silicone rubber using rheological methods.The effects of the vinyl-to-silanehydride molar ratio,curing temperature,and the active hydrogen content of the hydrogen-containing silicone oil on the vulcanization behavior were examined.Fur-thermore,the role of shear-induced molecular orientation on the curing characteristics was explored.Rheological results demonstrate that the gel point time is regulated by several competing factors:a higher vinyl-to-silanehydride ratio,in-creased temperature,and a greater active hydrogen content all contribute to an earlier gel time.Conversely,pre-shear-in-duced orientation of the silicone polymer chains was found to delay gelation,slowing down the crosslinking reaction.关键词
加成型双组分液体硅橡胶/交联硫化/流变学/预剪切Key words
additive two-component liquid silicone rubber/crosslinking curing/rheology/pre-shear分类
化学化工引用本文复制引用
赵炳祺,裴文宇,初朝阳,付中禹..加成型双组分液体硅橡胶交联硫化反应进程研究[J].中国塑料,2026,40(1):85-90,6.
