信阳师范大学学报（自然科学版）2026，Vol.39Issue(1)：66-73,8.DOI:10.3969/j.issn.2097-583X.2026.01.009
零价铁掺杂氮化碳吸附水中卡马西平性能研究
Study on the adsorption of carbamazepine by zero valent iron doped carbon nitride in water
摘要
Abstract
Zero valent iron doped carbon nitride(Fe@N/C)was synthesized to address the shortcomings of insufficient adsorption performance and poor solid-liquid separation performance of traditional carbon materials.Compared to carbon nitride(N/C),Fe@N/C had a higher BET surface area,pore volume and pore size,facilitating the exposure of N-and O-contained active sites,as well as the adsorption of pollutants.Carbamazepine(CBZ)was selected as the target pollutant,and the effect of solution pH,adsorption time and pollutant concentration on the adsorption performance of Fe@N/C was studied in detail.The results indicated that CBZ could be adsorbed onto Fe@N/C in a wide pH range.The adsorption process conformed to the pseudo-second order kinetic model and Langmuir isothermal model.The maximum adsorption capacity of Fe@N/C obtained by fitting with Langmuir isothermal model reached to 56.88 mg/g.Fe@N/C exhibited good reusability,and the adsorbent can be quickly separated from water using a magnet after adsorption.The adsorption mechanism indicated that CBZ was adsorbed onto Fe@N/C through π-π electron donor acceptor interactions and hydrogen bonding.关键词
零价铁/氮化碳/吸附/卡马西平Key words
zero valent iron/carbon nitride/adsorption/carbamazepine分类
化学化工引用本文复制引用
许飞亚,姬亚军,方堃,金紫荷,郑凌云..零价铁掺杂氮化碳吸附水中卡马西平性能研究[J].信阳师范大学学报（自然科学版）,2026,39(1):66-73,8.基金项目
河南省自然科学基金项目(252300421568) （252300421568）
河南省科技攻关计划项目(242102320078) （242102320078）
信阳师范大学青年科研基金项目(2024-QN-043) （2024-QN-043）
信阳师范大学"南湖学者奖励计划"青年项目 （）
河南省水土环境污染协同防治重点实验室开放基金项目(KLSPWSEP-A05) （KLSPWSEP-A05）
