信阳师范大学学报（自然科学版）2026，Vol.39Issue(1)：74-78,5.DOI:10.3969/j.issn.2097-583X.2026.01.010
对甲基苯硫酚功能化的螺-9,9'-氧杂蒽芴的设计合成及其光电性质
Design,synthesis and photoelectric properties of the p-methylthiophenol functionalized spiro-9,9'-oxanthrene fluorene
摘要
Abstract
A novel spiro compound 2,7-di(4-methylthiophenol)-spiro-9,9'-oxanthrene fluorene(DMePhS-SFX)was successfully prepared by functionalizing spiro-9,9'-oxanthrene fluorene(SFX)with p-methylthiophenol using cuprous oxide as a catalyst.The molecular structure was detailedly characterized by high resolution mass spectrometry,hydrogen spectroscopy and carbon spectroscopy.The data of thermogravimetric analysis showed that the thermal decomposition temperature of DMePhS-SFX was as high as 375 oC with 5%weight loss.The UV absorption and fluorescence spectra showed that the compound had intense absorption ranging from 220 to 370 nm,and the wavelength of its maximum emission peak was around 379 nm.The triplet energy level of the compound was 2.51 eV that was calculated from the first emission peak of phosphoresce luminescence at low temperature,which indicated that the compound could be used as host material to prepare red and green phosphorescent devices.The highest occupied orbit(HOMO)and the lowest unoccupied orbit(LUMO)energy levels were-5.88 eV and-2.16 eV,respectively,which were obtained by cyclic voltammetry.关键词
螺-9,9'-氧杂蒽芴/对甲基苯硫酚/热稳定性/前线分子轨道Key words
spiro[fluorene-9,9'-xanthene]/p-methylthiophenol/thermal stability/frontier molecular orbital分类
化学化工引用本文复制引用
赵祥华,王睿颖,李蕊蕊,李嘉欣,李玥,解令海..对甲基苯硫酚功能化的螺-9,9'-氧杂蒽芴的设计合成及其光电性质[J].信阳师范大学学报（自然科学版）,2026,39(1):74-78,5.基金项目
国家自然科学基金项目(61405170) （61405170）
