煤矿安全2026，Vol.57Issue(1)：11-20,10.DOI:10.13347/j.cnki.mkaq.20241777
季铵盐类表面活性剂对长焰煤甲烷解吸关键官能团的影响研究
Study on the influence of quaternary ammonium surfactants on key functional groups of methane desorption in long-flame coal
摘要
Abstract
Coal modification treatment is an important technical means to improve the methane desorption performance of coal and the permeability of coal seam,so as to improve the ability of coal seam gas extraction.Three kinds of quaternary ammonium surfact-ants were prepared into solution to modify long-flame coal,and the influence of quaternary ammonium surfactants on the key chem-ical structure of long-flame coal was studied.Based on Fourier transform infrared(FTIR)spectroscopy experiment,combined with peak-splitting fitting method to calculate relevant structural parameters,this study aims to clarify the variation characteristics of key functional groups in coal samples during methane adsorption and evaluate methane desorption capacity.The results show that the treatment of quaternary ammonium surfactants does not change the position of infrared absorption peak,but only affects the absorp-tion peak intensity and the relative content of functional groups.After the treatment of quaternary ammonium surfactants,the oxy-gen functional groups and condensation degree parameters of long flame coal are reduced.In particular,after benzalkonium bromide solution treatment with a mass fraction of 0.1%,the absorption peak area of aromatic structure decreased by 35.56%,maturity para-meter decreased by 96.8%,aliphatic chain length increased by 61.2%,and the aromatic ring condensation degree parameter de-creased by 58.56%.By analyzing the relationship between structural parameters and methane desorption capacity,it is found that 0.1%benzalkonium bromide solution has the most significant effect on the desorption capacity of long-flame coal.关键词
表面活性剂/红外光谱/分峰拟合/结构参数/瓦斯解吸Key words
surfactant/infrared spectrum/peak fitting/structural parameters/methane adsorption分类
矿业与冶金引用本文复制引用
刘雅欣,蔡峰,张潜,王金露..季铵盐类表面活性剂对长焰煤甲烷解吸关键官能团的影响研究[J].煤矿安全,2026,57(1):11-20,10.基金项目
安徽省高校协同创新资助项目(GXXT-2020-057) （GXXT-2020-057）
