色谱2026，Vol.44Issue(1)：78-91,14.DOI:10.3724/SP.J.1123.2025.06001
高降解效率分子印迹光催化剂的制备及其选择性降解性能
Fabrication of high-degradation-efficiency molecularly imprinted photocatalysts and its selective degradation performance
摘要
Abstract
Molecularly imprinted photocatalysts(MIPCs),which integrate specific molecular recognition with photocatalytic degradation capabilities,hold great promise for the selective and efficient removal of trace pollutants from complex environmental matrices.However,conventional surface-imprinting layers coated on photocatalysts often cause light-shielding effects,thereby re-ducing the photocatalytic efficiency of MIPCs.To overcome this limitation,the present study proposes a heterojunction-based interfacial in-situ imprinting strategy.In this approach,molecular imprinting cavities are directly constructed at the interface of composite photocatalysts.This design not only avoids the negative impact of surface shielding but also facilitates interfacial charge transfer,thus achieving a synergistic enhancement of both molecular recognition selectivity and photocatalytic efficiency.Based on this concept,a highly efficient molecularly imprinted photocatalyst,BiOBr-Cu/ppyr-MIPs,was successfully fabricated.The synthesis utilized surface molecular imprinting tech-nology with the organic pollutant acid orange(AO)as the template molecule,and BiOBr-Cu/polypyrrole(ppyr)composite as the heterojunction matrix.Polypyrrole,introduced as a conductive polymer,served as the imprinting layer that promotes charge migration.The synthesis conditions,including monomer amount and polymerization time,were systematically optimized to maximize imprinting efficiency and photocatalytic performance.The obtained BiOBr-Cu/ppyr-MIPs were comprehensively characterized.Scanning electron microscopy(SEM)revealed a well-defined morphology with uniformly distributed imprinted layers.X-ray diffraction(XRD)analysis confirmed that the introduction of the polypyrrole-based imprinting layer did not significantly alter the crystal structure of the BiOBr-Cu composite.Fourier-transform infrared spectroscopy(FTIR)showed characteristic peaks attributable to the pyrrole ring,such as C-H in-plane bending,C-H stretching,and C=N stretching vibrations,indicating successful incorporation of the polypyrrole framework.X-ray photoelectron spectroscopy(XPS)further confirmed the formation of the imprinted layer,with increased proportions of C-N and O=C bonding components observed in the C 1s and O 1s spectra,respectively.Optical and photoelectronic properties were also evaluated.UV-vis diffuse reflectance spectroscopy(DRS)revealed a significant red-shift and broader light absorption in the visible range,attributed to the presence of the polypyrrole layer.Photoluminescence(PL)spec-troscopy demonstrated a marked decrease in emission intensity,indicating that the recombination of photogenerated electron-hole pairs was effectively suppressed,which correlates with enhanced charge separation.Adsorption experiments indicated that BiOBr-Cu/ppyr-MIPs exhibited rapid adsorption kinetics,reaching equilibrium within 30 min and fitting a pseudo-second-order kinetic model.The maximum adsorption capacity was determined to be 40.9 μmol/g,consistent with the Freundlich isotherm model,suggesting a heterogeneous adsorption process with multilayer ad-sorption behavior.Photocatalytic degradation studies,optimized by adjusting catalyst dosage,initial pollutant concentration,and solution pH,showed a 2.04-5.79-fold enhancement in degradation efficiency compared to reference materials.The composite also exhibited excellent reusability,maintaining 90.7%of its initial performance after five consecutive cycles.Importantly,the material demonstrated strong molecular recognition capability,with an imprinting factor(IF)of 2.96 and a selectivity coefficient(Kselectivity)exceeding 1.79,indicating effective discrimination between the template molecule and structural analogs.Mechanistic investigations revealed that the interfacial polypyrrole imprinting layer not only contributed to selective adsorption but also facilitated targeted degradation pathways,thus achieving integrated selectivity and catalytic activity.In summary,this work introduces a novel interfacial in-situ imprinting strategy that overcomes key limitations of conventional MIPCs.The proposed design offers a generalizable approach for developing molecularly imprinted photocatalysts with both superior degradation efficiency and selectivity.关键词
分子印迹/选择性去除/聚吡咯/溴氧化铋Key words
molecular imprinting/selective removal/polypyrrole/bismuth oxobromide分类
化学化工引用本文复制引用
张军杰,宋亚菲,刘艳,田雪蒙,高瑞霞..高降解效率分子印迹光催化剂的制备及其选择性降解性能[J].色谱,2026,44(1):78-91,14.基金项目
国家自然科学基金(22374113). National Natural Science Foundation of China(No.22374113). （22374113）
