日用化学工业（中英文）2026，Vol.56Issue(1)：82-87,6.DOI:10.3969/j.issn.2097-2806.2026.01.010
有机硅酮胶负载钯催化剂在Heck反应中的应用
Application of metal palladium catalyst supported on organosilicone glue in Heck reaction
摘要
Abstract
Metal catalysis plays a crucial role in the Heck reaction,but it is prone to issues such as metal residue.In response to this issue,this article has developed a new way of encapsulating metal catalysts,which involves uniformly mixing the metal catalyst with organic silicone adhesive or uniformly mixing the metal catalyst with Fe3O4 and organic silicone adhesive.The resulting supported catalysts or magnetic supported catalysts are less prone to fragmentation,maintain good catalytic activity,and are easier to weigh and transfer,while also being readily filterable and recoverable.Experiments show that after 7 cycles of use,the organic silicone gel supported palladium catalyst(Pd/C@Glue)can still achieve a product yield of 85%in the Heck reaction,indicating that Pd/C@Glue has a high catalytic cycling efficiency in the Heck reaction.In addition,Pd/C@Glue is cycled 7 times in the Heck reaction,and the residual palladium content in the reaction solution is all below 26 ppm,indicating a low amount of metal leaching in the reaction solution.In order to achieve magnetic recovery of catalysts,a novel magnetic supported catalyst is obtained by simultaneously loading Fe3O4 and palladium catalysts onto organic silicone gel(Pd/C-Fe3O4@Glue)in this paper.Experiments show that the magnetic catalyst has good catalytic effect after multiple cycles of use.关键词
有机硅酮胶/催化剂载体/催化作用/Heck反应/金属残留/回收Key words
organosilicone gel/catalyst support/catalysis/Heck reaction/metal residue/recovery分类
化学化工引用本文复制引用
周平萍,徐磊,吴酉芝,纪婧,焦凌霞..有机硅酮胶负载钯催化剂在Heck反应中的应用[J].日用化学工业（中英文）,2026,56(1):82-87,6.基金项目
高校"双一流"建设上海市揽蓄计划B类人才项目(z32010.21.01) （z32010.21.01）
