低碳化学与化工2026，Vol.51Issue(1)：1-15,15.DOI:10.12434/j.issn.2097-2547.20250096
CO2加氢制芳烃反应路径与催化剂研究进展
Research progress on reaction pathways and catalysts for CO2 hydrogenation to aromatics
摘要
Abstract
Under the dual challenges of global warming and fossil energy depletion,CO2 hydrogenation to aromatics provides a green pathway for carbon resource recycling.CO2 hydrogenation to aromatics mainly focuses on two reaction pathways:CO2-modified Fischer-Tropsch synthesis(CO2-FTS)and methanol-mediated pathway.The reaction mechanisms and key intermediates of CO2-FTS and methanol-mediated pathways for the production of aromatics were reviewed,and the recent progress on catalyst structure design and optimization was summarized.The effects of additive type,support structure,acidity and structure modulation of zeolite molecular sieves,and the distance of active components in the bifunctional catalysts on the catalytic performance of CO2 hydrogenation to aromatics were highlighted.The synergistic effect of CO2 hydrogenation and arylation reaction as well as the formation of hydrogenation intermediates are the key factors influencing the performance of the catalysts.Finally,the application prospects of the catalysts for CO2 hydrogenation to aromatics were discussed,providing a reference for promoting the development in green chemical technology.关键词
CO2加氢/芳烃/双功能催化剂/反应路径Key words
CO2 hydrogenation/aromatics/bifunctional catalysts/reaction pathways分类
化学化工引用本文复制引用
何水森,王丽,王寒露,林存辉,单书峰,范钦臻,曾兴业..CO2加氢制芳烃反应路径与催化剂研究进展[J].低碳化学与化工,2026,51(1):1-15,15.基金项目
广东省基础与应用基础研究基金(2024A1515013253) （2024A1515013253）
广东省普通高校劣质油加工重点实验室(2018KSYS007) （2018KSYS007）
广东石油化工学院人才引进项目(2024rcyj1019). （2024rcyj1019）
