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CO2驱井下缓蚀剂的优选与缓蚀机理研究

李俊仪 魏旭 李山川 龙媛媛 董晓通 董浩文

安全、健康和环境2026,Vol.26Issue(1):40-49,10.
安全、健康和环境2026,Vol.26Issue(1):40-49,10.DOI:10.3969/j.issn.1672-7932.2026.01.008

CO2驱井下缓蚀剂的优选与缓蚀机理研究

Optimization and Corrosion Inhibition Mechanism Research of Downhole Corrosion Inhibitors for CO2 Flooding

李俊仪 1魏旭 1李山川 2龙媛媛 1董晓通 1董浩文3

作者信息

  • 1. 中国石化胜利油田技术检测中心,山东 东营 257000
  • 2. 中国石化胜利油田CCUS项目部,山东 东营 257000
  • 3. 中国石化胜利油田(青岛)技术研发中心,山东 青岛 266075
  • 折叠

摘要

Abstract

In response to the severe downhole CO2 corrosion issue associated with high water content during the large-scale exploitation of CO2 flooding in Shengli Oilfield,a novel high-temperature resistant and anti-CO2 corrosion inhibitor was compounded and selected using monomeric corrosion inhibitors,including imidazoline,quaternary ammonium salt,thiourea,alkanolamine,and fatty alcohol.Through testing,the optimal corrosion inhibitor formulation consists primarily of 20%imidazoline+10%quaternary ammonium salt+4%thiourea+10%alcoholamine.Experiments demonstrated that at dosing concentrations above 200 mg/L,corrosion inhibition rates consistently achieved 85%and above,with applicability across varying temperatures,flow rates,and CO2 pressures.Research on the corrosion inhibition mechanism indicated that the adsorption process follows the Langmuir adsorption model,which increases the charge transfer resistance on the metal surface and suppresses the anodic corrosion process,thereby significantly reducing corrosion on the steel surface.Field tests demonstra-ted that at a dosage concentration of 200 mg/L,the downhole corrosion rate can be controlled below 0.076 mm/a,meeting the protection requirements.

关键词

油气田/CO2驱/井下/高温高压/CO2缓蚀剂/缓蚀率/缓蚀机理

Key words

oil and gas field/CO2 flooding/downhole/high temperature and pressure/CO2 corrosion in-hibitor/corrosion inhibition rate/corrosion inhibition mechanism

分类

资源环境

引用本文复制引用

李俊仪,魏旭,李山川,龙媛媛,董晓通,董浩文..CO2驱井下缓蚀剂的优选与缓蚀机理研究[J].安全、健康和环境,2026,26(1):40-49,10.

基金项目

中国石化集团公司科技项目(P23043),CO2驱注采输系统腐蚀与安全风险防控关键技术. (P23043)

安全、健康和环境

1672-7932

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