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酸酐固化型环氧树脂在风电叶片化学降解回收中的应用研究

王蒙 武德涛 吴福梅 董阳

热力发电2026,Vol.55Issue(1):39-47,9.
热力发电2026,Vol.55Issue(1):39-47,9.DOI:10.19666/j.rlfd.202505087

酸酐固化型环氧树脂在风电叶片化学降解回收中的应用研究

Chemical degradation and recovery technology of anhydride-cured epoxy resin for wind turbine blades

王蒙 1武德涛 2吴福梅 2董阳2

作者信息

  • 1. 国能铁路装备有限责任公司,北京 100089
  • 2. 北京低碳清洁能源研究院,北京 102211
  • 折叠

摘要

Abstract

The anhydride-cured epoxy resin can be made into structural parts such as wind turbine blades and girders by pultrusion process.After crosslinking,it is difficult to degrade and recycle,which is one of the difficulties in the treatment of wind turbine blades.Methyl tetrahydro phthalic anhydride is a kind of anhydride curing agent.The effects of different liquid organic amines,different catalysts and different process conditions on the degradation of epoxy resin block cured by this anhydride were studied,and the best combination of degradation solution and degradation catalyst and degradation process conditions were determined,which realized the rapid degradation of anhydride cured epoxy system.At the same time,the degraded products were extracted and separated,and detected by infrared ray(IR)and nuclear magnetic resonance(NMR),and the main components of the recovered products were determined.Moreover,the degradation mechanism of the anhydride-cured epoxy resin by liquid organic amine was deduced,which provided a new idea and beneficial exploration for chemical recovery and reuse of the anhydride-cured epoxy resin.

关键词

风电叶片/有机胺/酸酐/环氧树脂/降解

Key words

wind turbine blades/organic amines/anhydride/epoxy resin/degradation

引用本文复制引用

王蒙,武德涛,吴福梅,董阳..酸酐固化型环氧树脂在风电叶片化学降解回收中的应用研究[J].热力发电,2026,55(1):39-47,9.

基金项目

国家能源集团科技创新项目(GJNY-20-141) Scientific and Technological Innovation Project of National Energy Group(GJNY-20-141) (GJNY-20-141)

热力发电

1002-3364

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