山东科学2026，Vol.39Issue(1)：121-132,12.DOI:10.3976/j.issn.1002-4026.2025049
燃煤过程中持久性有机污染物排放研究进展
Research progress on the emissions of persistent organic pollutants during coal combustion
摘要
Abstract
Persistent organic pollutants(POPs)generated during coal combustion have become a global focus of environmental governance because of their environmental persistence,bioaccumulation potential,and toxic effects.This study systematically reviews the formation mechanisms,emission characteristics,control technologies,and health risks of coal-derived POPs,such as polycyclic aromatic hydrocarbons(PAHs),halogenated PAHs(HPAHs),polychlorinated biphenyls(PCBs),and dioxins and furans.This study shows that POP formation is regulated by chemical kinetic pathways(precursor generation,halogenation,and surface-catalyzed synthesis)and the coupled effects of combustion conditions,coal properties,and fly ash catalysis.Their emission intensity is determined by the synergistic effects of combustion parameters,coal quality,and end-of-pipe control technologies.Remarkable heterogeneity exists in POP emissions from different combustion devices:PAHs are predominantly enriched in fine particles(particulate matter 2.5,PM2.5),whereas emissions of HPAHs and PCBs are considerably influenced by coal chlorine content and combustion technologies.Current precombustion treatment,in-combustion control,and postcombustion technologies partially reduced POPs;however,breakthroughs are needed for identifying emerging pollutants,analyzing cross-media migration mechanisms,and improving global governance frameworks.Human exposure to POPs through inhalation and dietary intake may cause respiratory,immune,and reproductive system diseases,with health risks exceeding safety thresholds in some regions.Future research should focus on the characteristics of emerging pollutants,optimizing synergistic emission reduction technology systems,and improving multimedia risk assessment frameworks.关键词
燃煤/持久性有机污染物/排放特征/减排技术Key words
coal combustion/persistent organic pollutants/emission characteristics/reduction technologies分类
资源环境引用本文复制引用
曹善勇,李玉洲,孙苗青,陈令强,徐劲松,王刚,陈相峰,赵凌曦..燃煤过程中持久性有机污染物排放研究进展[J].山东科学,2026,39(1):121-132,12.基金项目
山东企业技术创新项目(2024537010000879,2024537020000144) （2024537010000879,2024537020000144）
